1
2008-01-2052
Development and Design of a Low Temperature Solid Waste
Oxidation and Water Recovery System
James A. Nabity, Erik W. Andersen, Jeffrey R. Engel
TDA Research, Inc., 12345 W. 52
nd
Ave, Wheat Ridge, CO 80033
David T. Wickham
Reaction Systems LLC, Golden, CO 80401
John W. Fisher
NASA Ames Research Center, Moffett Field, CA 94035
Copyright © 2008 Society of Automotive Engineers, Inc.
ABSTRACT
In February 2004 NASA released “The Vision for Space
Exploration.” The goals outlined in this document
include extending the human presence in the solar
system, culminating in the exploration of Mars. A key
requirement for this effort is to identify a safe and
effective method to process waste. Methods currently
under consideration include incineration, microbial
oxidation, pyrolysis, drying, and compaction. Although
each has advantages, no single method has yet been
developed that is safe, recovers valuable resources
including oxygen and water, and has low energy and
space requirements. Thus, the objective of this work is
to develop a low temperature oxidation process to
convert waste cleanly and rapidly to carbon dioxide and
water.
Previously, TDA Research, Inc. demonstrated the
potential of a low temperature dry oxidation process
using ozone in a small laboratory reactor. Currently,
TDA and NASA Ames Research Center are developing
a pilot scale low temperature ozone oxidation system to
convert organic waste to CO
2
and H
2
O. The system
also disinfects the waste and remaining water, and
recovers not only the water content of the waste but also
generates additional water that can be utilized by the
crew. Tests are being conducted with model wastes in a
reactor design that maximizes the contact between the
reactants by mixing the waste with water, which also
makes the oxidation process extremely selective to CO
2
and H
2
O and mitigates the rapid combustion events that
were seen in the dry oxidation reactor. An ozone
recycle loop was recently added to the system, which
significantly increased the waste oxidation rates. The
reactor operating conditions were then optimized using
the design of experiments technique to maximize the
waste oxidation rate. Currently, a pilot scale, fully
automated system is being designed that will be capable
of handling many different types of waste. The waste
oxidation rates achieved to date, along with current
waste generation rate models, indicate that all of the
waste from a single crew member in one day can be
processed in a vessel ranging in size from 8.2 liters (2.2
gallons) for a short term mission to 9.9 liters (2.6
gallons) for a long term mission. In addition, if the
system were used solely as a fecal matter oxidizer the
reactor size would be only 0.7 liters. At the conclusion
of the project the system will be delivered to NASA
Ames for evaluation.
INTRODUCTION
A critical need for space missions is an effective method
to control solid waste. The current estimates of solid
waste generation rates are about 1.69 kg/CMD
(kilograms per crew member day) for long duration
space missions and 1.39 kg/CMD for short term
missions
1
. If one assumes that a 180 day mission to
Mars will include six crew, a total of 1825 kg of waste will
be generated. Without processing and using the highest
densities that have been achieved to date of 64 kg/m
3
, a
space of approximately 28.5 m
3
would be required to
contain this waste
2
. In addition to occupying valuable
space, leaving waste unprocessed could cause the crew
to be exposed to odors and biohazards, which would be
a serious threat to their health and morale.
Moreover, since leaving waste on the surface of Mars is
undesirable, all waste generated on the way to the
planet along with that produced during the surface stay
is to be transported back. Thus, the additional launch