Registered Charity Number 207890 Accepted Manuscript This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted Manuscripts are published online shortly after acceptance, which is prior to technical editing, formatting and proof reading. This free service from RSC Publishing allows authors to make their results available to the community, in citable form, before publication of the edited article. This Accepted Manuscript will be replaced by the edited and formatted Advance Article as soon as this is available. To cite this manuscript please use its permanent Digital Object Identifier (DOI®), which is identical for all formats of publication. More information about Accepted Manuscripts can be found in the Information for Authors. Please note that technical editing may introduce minor changes to the text and/or graphics contained in the manuscript submitted by the author(s) which may alter content, and that the standard Terms & Conditions and the ethical guidelines that apply to the journal are still applicable. In no event shall the RSC be held responsible for any errors or omissions in these Accepted Manuscript manuscripts or any consequences arising from the use of any information contained in them. www.rsc.org/dalton ISSN 1477-9226 Dalton Transactions An international journal of inorganic chemistry 1477-9226(2010)39:1;1-K www.rsc.org/dalton Volume 39 | Number 3 | 21 January 2010 | Pages 657–964 Dalton Transactions PAPER Manzano et al. Experimental and computational study of the interplay between C–H/pand anion–pinteractions COMMUNICATION Bu et al. Zinc(II)-boron(III)-imidazolate framework (ZBIF) with unusual pentagonal channels prepared from deep eutectic solvent Dalton Transactions