S1
Unexpected Evolution of Optical Properties in Ir-Pt Complexes Upon
Repeat Unit Increase: Towards an Understanding of the
Photophysical Behaviour of Organometallic Polymers
Ahmed M. Soliman, Daniel Fortin, Eli Zysman-Colman* and Pierre D. Harvey*
Département de chimie, Université de Sherbrooke,
2500 Boul. Université, Sherbrooke, QC, J1K 2R1
Pierre.Harvey@usherbrooke.ca ; Eli.Zysman-Colman@usherbrooke.ca
SUPPORTING INFORMATION
Table of Contents: Pages
Experimental section S2-S6
Absorption and emission spectra of individual complexes S7-S10
Excitation and absorption at 77K S11
Spectroscopic and photophysical data of 1, 2, 3, 6 and 7 in 2-MeTHF S12
Cyclic voltammograms for 4, 2, 3, 7 and 6 S13
Energy and composition of TD-DFT calculated transitions for 7 S14
1
H,
13
C and
31
P NMR spectra of 7 and 11 S15-S20
References S21
Electronic Supplementary Material (ESI) for Chemical Communications
This journal is © The Royal Society of Chemistry 2012