Desalination 227 (2008) 327–333
Nitrate removal of brackish underground water by chemical
adsorption and by electrodialysis
M.A. Menkouchi Sahli
a
, S. Annouar
b,c
, M. Mountadar
b
, A. Soufiane
c
,
A. Elmidaoui
a*
a
Separation Processes Laboratory, Faculty of Sciences, B.P. 1246, Kenitra, Morocco
Tel. /Fax: +212 (7) 37 30 33; email: elmidaouiazzedine@yahoo.fr
b
Unit of Analytic Chemistry and Environmental Engineering;
c
Laboratory of Coordination Chemistry and Analysis,
Faculty of Sciences, El Jadida, Morocco
Received 14 February 2007; Accepted 30 July 2007
Abstract
Nitrate content has increased in Morocco, especially in underground water of agrarian areas. Several processes
including degradation processes and separation processes can remove nitrate from water. Two separating processes
were studied to remove nitrate from brackish underground water: adsorption on industrial animal waste and
electrodialysis equipped by anion monovalent membrane. The results show that a desired product water quality can
easily be obtained by electrodialysis contrary to chemical adsorption which requires a great reactional surface.
Keywords: Brackish water; Denitration; Adsorption; Chitosan; Electrodialysis
1. Introduction
Today the protection of health and the respect
of the environment are among man’s first pre-
occupations. One of the most important concerns
is the contamination of underground waters by
the nitrates. In Morocco, as in several other
countries, this contamination worsens continually
following the demographical and economical
*Corresponding author.
development which main origin comes from agri-
cultural practices [1,2]. The main sanitary risks to
consider during of the consumption of nitrates in
quantity passing these norms required by OMS to
50 ppm are methaemoglobinaemia and formation
of the nitrosamines [3]. Facing these permanent
risks and the difficulty to warn of this contami-
nation, the elimination of these ions becomes a
necessity.
Various methods have been tested for the
denitration of waters, among others: biological
0011-9164/08/$– See front matter © 2008 Published by Elsevier B.V.
doi:10.1016/j.desal.2007.07.021