Expression and characterizaton of Trichoderma reesei endoglucanase II in
Pichia pastoris under the regulaton of the GAP promoter
Kezia Abib Yerah Tjandra
1
, Kartka Sari Dewi
2,*
, Asrul Muhamad Fuad
2
, Trisant Anindyawat
2
1
Department of Industrial Biotechnology, Brawijaya University, Jalan Veteran, Malang 165145, Indonesia
2
Research Centre for Biotechnology, Indonesian Insttute of Sciences, Jalan Raya Jakarta‐Bogor Km.46, Cibinong 16911, Indonesia
*Corresponding author: kartka.sari.dewi@lipi.go.id
SUBMITTED 22 April 2020 REVISED 30 August 2020 ACCEPTED 7 October 2020
ABSTRACT Trichoderma reesei is known to be one of the organisms capable for producing various types of cellulase in
high concentratons. Among these cellulases, the highest catalytc efciency of endoglucanases II (EGII, EC 3.2.1.4) are
considered important for industrial applicaton. The characterizaton of the EGII is necessary since it is widely used in
high‐temperature reactons in the industries. In this study, the recombinant EGII protein was expressed in Pichia pastoris
and it has a molecular mass of approximately 52 kDa. Recombinant EGII was purifed using Ni‐NTA afnity chromatography
and characterized by SDS‐PAGE and western blot analyses. The enzyme actvity of recombinant EGII was measured using
the Nelson Somogyi method to determine its optmum pH and temperature. The result showed that the maximum EGII
expression was achieved afer 72 h of culture incubaton. The crude enzyme has optmum actvity at pH 5.0, resultng in
16.3 U/mL and 14.6 U/mL actvity at 40 °C and 50 °C, respectvely. While the purifed enzyme gave the specifc actvity
of 115.7 U/mg under the optmum conditon. Finally, our study demonstrated that recombinant EGII could retain the
endoglucanase actvity for 89% and 80% at 40 °C and 50 °C, respectvely.
KEYWORDS Endoglucanase II; GAP promoter; Trichoderma reesei; Pichia pastoris; Nelson‐Somogyi assay
Indonesian Journal of Biotechnology
VOLUME 25(2), 2020, 127‐134 | RESEARCH ARTICLE
1. Introducton
Trichoderma reesei is a wellstudied fungus that is capa
ble of producing large amounts of various cellulases. This
fungus secretes at least six types of cellulases that con
sist of two types of cellobiohydrolases and four endoglu
canases (Knott et al. 2014). These enzymes are exten
sively used in several industries, such as laundry deter
gent, textile and pulp, paper industry, and potential for
bioenergy production. Thereby, this fungus is industri
ally relevant to meet the target production level of cellu
lases. Nowadays, the engineering of cellulase into a high
performance enzyme for biomass hydrolysis and other in
dustrial applications becomes the major research priority.
However, various industrial processes and conditions (par
ticularly in different temperature and pH conditions) re
main a challenge. The cellulase excreted from T. reesei
cannot withstand a long period of exposure at high tem
perature and pH during its reaction process, which leads
to the leveling off of enzymatic activity (Akbarzadeh et al.
2014).
Among cellulases produced by T. reesei, endoglu
canase II (EGII; EC 3.2.1.4) is predominant and showed
the highest catalytic proficiency. The EGs activity of T.
reesei is known to decrease about 55% when EGII was
absent in the secretory complex of EGs (Qin et al. 2008;
Boonvitthya et al. 2013). This evidence revealed that the
presence of EGII is crucial for lignocellulosic biomass hy
drolysis and other industrial applications. Several stud
ies reported that EGII production and characteristic im
provement were performed by improving the strain of se
creting microorganisms, protein engineering, and recom
bination (Ito et al. 2004; Liang et al. 2011; Charoenrat
et al. 2013). Thereby, there is still ample scope for im
provement, particularly to produce EGII in a heterologous
expression system to facilitate protein engineering work.
Several heterologous expression has been carried out to
produce endoglucanases in various host microorganisms,
including Escherichia coli, Yarrowia lipolytica, Saccha
romyces cerevisiae, and Pichia pastoris (Nakazawa et al.
2008; Qin et al. 2008; Boonvitthya et al. 2013; Akbarzadeh
et al. 2014). Yeast is commonly used for its ability to in
crease protein stability since the glycosylation process has
occurred. In consequence, the structural and thermal sta
bility of protein may increase due to the covalent bond for
mation. The covalent bond formation causes less dynamic
fluctuation and reduces protein molecules’ flexibility (Qin
and Qu 2014).
Pichia pastoris has negligible native protein produc
Indones J Biotechnol 25(2), 2020, 127‐134 | DOI 10.22146/ijbiotech.55604
www.jurnal.ugm.ac.id/ijbiotech
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