Sanchit et al Journal of Drug Delivery & Therapeutics. 2015; 5(6):14-17 14
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REVIEW ARTICLE
BIOLOGICALLY ACTIVE PYRIMIDINE HYDRAZONES
Srivastav Sanchit*, Luhach Kanishk, Shukla Chhama, Yadav Rajender
Department of pharmacy, IEC College of Engineering & Technology, Gr. Noida (UP), India-201308
*Corresponding Author’s Email: srivastavsanchit@gmail.com, Mobile No: +918800688147
Received 23 Sep 2015; Review Completed 14 Oct 2015; Accepted 15 2015, Available online 15 Nov 2015
1. INTRODUCTION
Medicinal chemistry is the branch of science that deals
mainly with the synthetic organic chemistry and
pharmacology of the drugs with special references to
structure including design, modifications and analysis of
drugs or chemical synthesis of lead compounds to make
them suitable for the mankind or animals with least
toxicity and optimum response
1
.
Heterocyclic chemistry is a very important branch of
organic chemistry and most of the organic synthetic or
semi synthetic compounds are heterocyclic in structural
properties. Its structure can be described with carbon
atoms in ring forming carbocyclic compound
2
.
The most common heteroatoms are Nitrogen, oxygen
and sulfur. But heterocyclic rings containing other
hetero atoms are having in broad variety. Heterocyclic
compounds can be classified as aliphatic and aromatic.
The aliphatic heterocyclics are the cyclic similarities of
amines, ethers, thio ethers, amides, etc.
Heterocyclic compounds are having importance in
various medicinal formulations and are present in a large
variety of drugs, most vitamins, natural products etc. In
addition to this biologically active compounds,
including antitumor, antibiotic, anti-inflammatory,
antidepressant, antimalarial, anti-HIV, antimicrobial,
antibacterial, antifungal, antiviral, antidiabetic,
herbicidal, fungicidal, anticonvulsant, and insecticidal
agents
3
.
1.1 Pyrimidine
Heterocyclic aromatic organic compound like benzene
or pyridine, having two nitrogen atoms at positions 1
and 3 of the six-membered ring; they have isomers in the
forms of diazine
4
Figure 1
ABSTRACT
Pyrimidine constitutes an important class of heterocycles in drug discovery & is very well known for their anticancer,
antimicrobial, antioxidant & antiviral activities. Hydrazones is a class of organic compounds with the structure R
1
R
2
C=NNH
2.
They are formed usually by the action of hydrazine on ketones or aldehydes & have efficient CNS depressant, analgesics
activity. In the same context, Schiff bases of pyrimidine hydrazones can be prepared by the reaction of “4-(4-Chloro-phenyl)-
6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid hydrazide” with various terpenes such as citral, camphor,
furfuraldehyde & menthone to make Schiff bases individually by refluxing them in the presence of glacial acetic acid (as
solvent) for at least 2hrs to yield their respective derivatives.
The present studies revealed that Pyrimidine hydrazone derivatives could be used to synthesize the compounds having potent
biological activities such as anticancer, antimicrobial, antioxidant, CNS depressant, analgesic & antiviral activities. All the
prepared derivatives were under investigation for their antimicrobial activity and likely to possess the same & desired action.
Keyword: Pyrimidine Hydrazones, Biological active Pyrimidine, Schiff Bases etc.