Materials Sciences and Applications, 2018, 9, 126-141
http://www.scirp.org/journal/msa
ISSN Online: 2153-1188
ISSN Print: 2153-117X
DOI: 10.4236/msa.2018.91009 Jan. 18, 2018 126 Materials Sciences and Applications
Corrosion Pattern of Pipeline Steel in
Petroleum Pipeline Water in the Presence of
Biomas Derived Extracts of Brassica oleracea
and Citrus paradise Mesocarp
Nnaemeka Chinedu Ngobiri, Kaine Okorosaye-Orubite
*
Department of Pure and Industrial Chemistry, University of Port Harcourt, Rivers State, Nigeria
Abstract
Corrosion inhibition characteristics of two biomass derived extracts from
outer leaves of Brassica oleracea (BO) and Citrus paradise mesocarps (CPM)
on pipeline steel were investigated using modified gravimetric method at am-
bient temperature (28 ± ˚C). Petroleum pipeline water was used to simulate a
pseudo-anaerobic corrosion cell. The result obtained showed that corrosion
was a continuous process in the closed system, while BO and CPM showed
near equivalence corrosion inhibition efficiency of 91.45% and 89.44% respec-
tively at the concentrations studied. The thermodynamic data suggests inhibi-
tion to be through molecular adsorption on metal surface.
Keywords
Adsorption, Corrosion, Modified Gravimetric, Pipeline Water,
Pseudo-Anaerobic
1. Introduction
The problem of metallic corrosion is an age long issue and mankind has not
ceased to find lasting solution. Though a natural process, the driving force has
been attributed to the energy imputed into metallic material during refining of
their ores. This thermodynamically inevitable process results to the indirect cost
of corrosion damages [1]. Many corrosion mitigation methods abound, one of
such is the application of corrosion inhibitors in metallic environments [2] [3].
Steel pipelines are used to transport domestic and industrial fluids because of
convenience. However, as metals, they are prone to worsening internal corrosion
How to cite this paper: Ngobiri, N.C. and
Okorosaye-Orubite, K. (2018) Corrosion Pa-
ttern of Pipeline Steel in Petroleum Pipeline
Water in the Presence of Biomas Derived
Extracts of Brassica oleracea and Citrus para-
dise Mesocarp. Materials Sciences and Appli-
cations, 9, 126-141.
https://doi.org/10.4236/msa.2018.91009
Received: October 20, 2017
Accepted: January 15, 2018
Published: January 18, 2018
Copyright © 2018 by authors and
Scientific Research Publishing Inc.
This work is licensed under the Creative
Commons Attribution International
License (CC BY 4.0).
http://creativecommons.org/licenses/by/4.0/
Open Access