Romanian Biotechnological Letters Vol. 15, No.3, 2010, Supplement
Copyright © 2010 University of Bucharest Printed in Romania. All rights reserved
ORIGINAL PAPER
109
Nanostructured thin films for prosthetic dentistry applications
Received for publication, April 6, 2010
Accepted, May 22, 2010
MADĂLINA PRODAN
1
, IULIANA STANESCU
1
, V. CIUPINA
1
, DOINA
GHEORGHIU
2
, COMSA STANCA
2
, V. EUGENIU
3
, G. PRODAN
1
1
“Ovidius” University of Constanţa, Constanta, 900527, Romania
2
The National Institute of Research and Development in Mechatronics and Measurement
Technique, Bucharest, 021591, Romania
3
Metav Research-Development Bucharest, 020011, Romania
mprodan@univ-ovidius.ro
Abstract
Nanostructured carbon thin film has a large application in different working area. These work will
present nanostructured carbon thin films obtained by TVA (Thermionic Vacuum Arc) method, with nanometric
size (thickness < 100nm). The most important feature of these films is hardness given by sp2-sp3 ratio of films
composition. Titan alloy are used frequently in biomedical application due to highly biocompatibility. The
resulted prosthetic from these coated alloy, with high hardness carbon films, lead on substantial improvement
quality, from mechanical point of view with about 100% related to other protection methods.
TVA method allows a morphological smoothly DLC (diamond like carbon) type carbon films to obtain.
The resulted DLC is thicker and has diamond properties, like: high hardness (3000-5000kg/mm
2
), small friction
coefficient (0,1-0,2), chemical inactive, abrasion hardness (1,6x10,9mm
3
/mN) and also electrical properties.
Obtained films were studied by electron microscopy techniques (TEM, SEM, HRTEM, EELS, SAED and
PED). PED (Precession of Electron Diffraction) method is recently developed and substantially improves the
crystalline structure studies by means of electron diffraction patterns acquisition very close to kinematical
condition. Also, the mechanical resistance was tested and compared for coated and uncoated alloys. The
geometry of used sample is cylindrical with 100 mm length and 3 mm diameter. Dynamic tensile and bend tests
were performed using method described by the SR EN 10002-1:2002 standard.
Dynamic tensile test show increasing of sample length from 4 mm (uncoated sample) to approximately
6 mm for coated sample, and the maximum stress and bending momentum values gives that carbon coated
samples are more elastic.
Keywords: prosthetic dentistry, TVA, DLC, SAED
Introduction
For applications in medical devices, nanostructured materials have unique properties
to interact with cells, proteins and human DNA. These materials are defined as materials
containing structural elements (i.e. clusters, crystallites or molecules) with dimensions range
from 1 to 100 nm. Recent advances in medical applications are the result of the development
of two complementary phenomena. First, is a natural evolution from micro to nano scale as
processing and characterization techniques become available. Second, the nanostructured
materials allow specific protein interactions, DNA, viruses and other biological structures at
the nano scale (HAN & al, [1]. Specific interactions between them and nanostructured
materials can generate biological features that are not possible when using micro materials
(PIELES & al, [2].
Field of nanostructured ceramic materials for medical applications are rapidly
evolving. As biomedical applications, pharmaceuticals and cosmetics are major target market
for suppliers of nanoparticles and nanotechnologies, in this stage we propose a description of
different types of nanoparticles, including nanoparticles of ceramics, metals and alloys in the