1
Selective Zn
2+
sensing using a modified bipyridine complex
Mahesh Akula, Patrick El Khoury, Amit Nag
*
and Anupam Bhattacharya
*
Birla Institute of Technology and Science-Pilani(Hyderabad Campus), Hyderabad-500078, Andhra Pradesh, India
e-mail: anupam@hyderabad.bits-pilani.ac.in. amitnag@hyderabad.bits-pilani.ac.in.
SUPPORTING INFORMATION
Contents:
Scheme & procedure for preparation of ligands
S1-S6: Characterization (
1
H &
13
C NMR)
S7: MALDI of the complex (PPQ-Zn-PPQ)
S8: Reversibility experiment
S9: Fluorescence titration
S10: pH titration
S11: Ratiometric sensing
S12-14: MALDI (with Co
2+
, Ni
2+
and Cu
2+
)
S15: UV-Visible spectra of PPQ
S16: TD DFT studies of PPQ and PPQ-Zn
2+
-PPQ
Electronic Supplementary Material (ESI) for RSC Advances.
This journal is © The Royal Society of Chemistry 2014