Hybrid Nano Plasmonics for Integrated Biosensor
Chii-Wann Lin
*a
, Jun-Haw Lee
b
, Nan-Fu Chiu
a
, Szu-Yuan Lee
a
, Kou-Chen Liu
c
, Feng-Yu
Tsai
d
, Chia-Yu Yen
e
, Chun-Nan Lee
f
*a
Inst. of Biomed. Eng.,
b
Inst. of Optcal Eng.,
d
Inst, of Mat. Sci and Eng.,
e
Dept. of Mech. Eng.,
f
Dept. of Clin. Lab. Sci. Med. Biotech., National Taiwan Univ., No.1, Sec.4, Roosevelt Rd., Taipei,
Taiwan 106;
c
Inst. of Opt. eng., Chang-Gang Univ.,
ABSTRACT
SPR biosensor with OLED and nano-grating for HBV LAMP product detection is reported. Directional emissions by grating-coupler
match the resonant condition of SP modes. Concentration changes result in color shift at specific angle. Real time detection of virus
load down to 5 copies/25 ul can be achieved in 30 minutes. Surface plasmon Resonant (SPR) biosensor has been used for
quantitative measurement of molecular interactions for its advantages of high sensitivity, label-free and real-time
detection. In this paper, we report recent efforts on further enhancement of SPR biosensors by the heterogeneous
integration of organic electroluminescence light source and nano-grating structure for the feasibility study on the fast and
high sensitivity detection of HBV isothermal amplification products, Mg
2
P
2
O
7
. We demonstrated the surface plasmon
coupled through hybrid nano-grating structure has highly directional emissions corresponding to the resonant condition
of surface plasmon modes on the Au/air interface and controllable plasmonics band-gap by pitch modulation. SPGCE
resulted in color change from yellowish green to orange at a certain viewing angle, when contacting glucose with
concentration increasing from 10 to 40%.
Keywords: (170.3890) Medical optics instrumentation; (240.6680) Surface plasmons
1. INTRODUCTION
Advancements in biotechnology and micro/nano-technologies have resulted in the fast evolution of biosensors and
biochips for applications in both diagnosis and therapy, for examples drug discovery and disease marker profiling based
on molecular recognition
1
. One of the most widespread label-free optical detection systems is surface-plasmon resonance
(SPR). The behavior of free electrons or plasma near a metallic-dielectric interface is a special type of light-matter
interactions. High-density electron gas, when subjected to collective longitudinal excitation or oscillation, will manifest
particle-like behavior. Analogous to phonons, magnons and excitons, such a phenomenon has been called “Plasmon”. It
occurs in the forms of bulk, surface, and particle plasmons, and research on the phenomenon has led to many important
applications in optoelectronics and biomedicine. The unique characteristics of non-labeling and real-time monitoring
have opened up a wide spectrum of novel developments in biochemical and biophysical applications, especially those
involving the dynamic interactions of bio-molecules at the solid/liquid or solid/gas interface. The most prevalent
implementation for product development is based on the prism coupling of Attenuate Total Reflection (ATR). With this
method, biochemical interactions on the sensor surface are monitored by observing the resonant behavior of surface
plasmon waves on the metal/dielectric interface. However, many of these systems require the uses of bulky high
refractive index coupling prism, external light source and detector to measure the resonant condition by reflectivity.
Currently, we are developing an integrated plasmonic device for a hand-held SPR system. We have developed three
components of such a system, including, multi-layer
2,3
, nano-grating
4,5
and active-plasmonics
6
for further minimization
of the whole system onto a disposable platform with controllable planar electroluminescence light source through
modulation of nanostructure as shown in Fig 1.
Fig. 1. Schematic diagram of the proposed hybrid nano-plasmonic sensor for biomolecular interactions.
Invited Paper
Optical Sensors and Biophotonics, edited by Xingde Li, Qingming Luo, Vasilis Ntziachristos, Yoshiaki Yasuno,
Proc. of SPIE-OSA-IEEE Asia Communications and Photonics, SPIE Vol. 7634, 76340O · © 2009 SPIE-OSA-IEEE
CCC code: 0277-786X/09/$18 · doi: 10.1117/12.853214
SPIE-OSA-IEEE/ Vol. 7634 76340O-1