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Archives of Hygiene Sciences Volume 6, Number 2, Spring 2017
© 2017 Publisher: Research Center for Environmental Pollutants, Qom University of Medical Sciences. All rights reserved.
• Arch Hyg Sci 2017;6(2): 214-220
• Journal Homepage: http://jhygiene.muq.ac.ir
RESEARCH ARTICLE
214
Naser Tavassoli
a
, Reza Ansari
a
*, Zahra Mosayebzadeh
a
a
Department of Chemistry, School of Science, University of Guilan, Rasht, Iran.
*Correspondence should be addressed to Dr. Reza Ansari, Email: ransari271@guilan.ac.ir
Water is crucial to survive all living organisms
on the earth, and access to safe drinking-water
is important as health and development issue at
a national, regional and local levels (1). One of
today's environmental challenges is the
excessive use of dyes for industrial and
domestic activities which it contaminates the
ground and surface water; therefore, it is
important to remove these dangerous organic
compounds from water and wastewater prior to
discharge into the environment (2-5). Water
pollution by synthetic organic dyes used in
textile, cosmetics, pulp and paper industries
etc., is mainly regarded as environmental and
ecological critical issues worldwide (4-7).
These industries produce considerable unfixed
dyes that in turn impart strong color, expelling
of these dyes into water bodies, produce a large
quantity of dyeing wastewater which needs to
treatment before being discharged into
waterways.
Due to the aromatic structures, synthetic dyes
have chemical stability; thus, they are difficult
to biodegrade, oxidizing and photo degradation,
giving water undesirable color, diminish light
penetration and oxygen gas solubility, so,
photosynthetic reactions of aquatic plants, will
be decreased, having toxic effects on human
health (8,9).
A-R-T-I-C-L-EI-N-F-O A-B-S-T-R-A-C-T
Article Notes:
Received: Oct. 2, 2016
Received in revised form:
Jan. 29, 2017
Accepted: Feb. 21, 2017
Available Online: Feb 28,
2017
Background & Aims of the Study: water pollution by synthetic organic dyes is mainly
regarded as environmental and ecological critical issues worldwide. In this research, magnetite
iron oxide/silica gel nanocomposite (termed as Fe
3
O
4
/SG) was synthesized chemically and then
used as an effective adsorbent for removal of sulfur dyes from aqueous solution.
Materials and Methods: The various parameters such as pH, sorbent dosage, initial dye
concentration, contact time and dye solution temperature were investigated in a batch system.
The equilibrium data were analyzed by Langmuir and Freundlich isotherm models.
Results: The experimental data fit well with pseudo-second-order kinetic model (R
2
≥0.998) and
conformed better to Langmuir isotherm model (R
2
≥0.997). The maximum adsorption capacity
for Fe
3
O
4
/SG obtained from the Langmuir model was 11.1mg/g. Evaluation of thermodynamic
parameters proved that the adsorption process was normally feasible, spontaneous and
exothermic.
Conclusion: It can be concluded that the Fe
3
O
4
/SG can be considered as a cost-effective and an
environmental friendly adsorbent for efficient removal of sulfur dyes from aqueous solutions.
Keywords:
Adsorption
Fe
3
O
4
coated silica
Sulfur dye
Isotherm
Iran.
Please cite this article as: Tavassoli N, Ansari R, Mosayebzadeh Z. Synthesis and Application of Iron Oxide/Silica
Gel Nanocomposite for Removal of Sulfur Dyes from Aqueous Solutions. Arch Hyg Sci 2017;6(2):214-220.
Synthesis and Application of Iron Oxide/Silica Gel
Nanocomposite for Removal of Sulfur Dyes from
Aqueous Solutions
Background