Universal Journal of Materials Science 6(4): 133-138, 2018 http://www.hrpub.org
DOI: 10.13189/ujms.2018.060403
Synthesis of Polymeric Composites Reinforced with
Unidirectional and Bidirectional Bamboo Fibers
Milene Muniz Eloy da Costa
*
, Santino Loruan Silvestre de Melo, Enio Pontes de Deus
Department of Metallurgical and Materials Engineering, Federal University of Ceará, Fortaleza, Ceará, Brazil
Copyright©2018 by authors, all rights reserved. Authors agree that this article remains permanently open access under
the terms of the Creative Commons Attribution License 4.0 International License
Abstract Due to environmental problems and
exhaustion related to materials provided from
non-renewable sources, the development of recycling
technologies using residue as raw material has grown
increasingly. Polypropylene (PP), a thermoplastic polymer,
despite be easily recycled, presents a decrease in their
mechanical properties after reprocessing cycles. In order to
solve this problem, reinforcements may be added,
producing a composite with better properties. The choosing
of the dispersed phase aimed to consider, especially, its
mechanical properties. Moreover, it was also considered
the orientations of the incorporated fibers at the composite
mechanical strength. In this scenario, a composite material
of polymer matrix from recycled PP reinforced
unidirectionally and bidirectionally with bamboo fibers
were prepared. The fibers were treated with modifiers in
order to increase the adhesion between polymer/fiber. The
results showed that the use of reinforcement improves the
mechanical properties of the polymer. Also, the superficial
treatments were effective, indicating that there was an
increase of the compatibility between the materials. It can
be also inferred that the orientation of the fibers has
directly influence at the final properties of the composite.
Keywords Recycled Polypropylene, Bamboo Fibers,
Reinforcement Orientation, Polymeric Composites,
Surface Modifiers
1. Introduction
Polymers are formed by macromolecules constituted by
the repetition of short chemical units called monomers [1].
Conventionally, polymers are prepared from petroleum
fractions, non-renewable and not biodegradable source,
contributing a lot for the residues generation. Therefore,
researchers and industry have been seeking alternatives to
minimize the impacts caused by improper and exaggerated
disposal of these materials. Thus, the reuse and recycling
are presented as management strategies of these residues,
also involving the deployment of industrial ecology, which
means that nothing is residue, but a raw material for a new
product [2, 3]. In addition, other aspects motivate these
processes, such as economy of energy (the manufacturing
of recycled plastic saves about 70% of energy), of financial
(reduction of expenses with cleaning and public health) and
environmental (reduction with the recovery of impacted
areas, such as rivers and lakes) [4].
According to surveys conducted in major Brazilian cities,
the recycling of plastics remains slow due to the lack of
selective waste collection associated with an efficient
waste sorting. The main polymers found in these urban
residues are high and low density polyethylene (HDPE and
LDPE), polyethylene terephthalate (PET), polyvinyl
chloride (PVC) and polypropylene (PP) [4, 5].
The PP is a polymer synthesized from propylene
monomer. It is a colorless material with excellent
mechanical properties related to its crystallinity. The
atactic PP, with all methyl groups allocated irregularly
along the chain, is the most used in the market [6, 7]. This
polymer is a semi-rigid, translucent, with a good
mechanical, electrical, thermal and chemical strength, etc.
[6, 8]. Furthermore, because it is a thermoplastic, the PP
has a great usability and can be formed easily, that is, a
widely recyclable material. However, the recycling of
polymers causes depletion of its mechanical properties
because it increases the amount of defects. These did not
significantly interfere with mechanical behavior until the
maximum force was reached. From this point, where the
propagation of cracks has a great influence on the
deformation until the rupture, the defects were
determinants in the deformation [8, 9]. This problem can
be solved with the mixture of the virgin and recycled PP,
which has yielded good results [9], or with the addition of
reinforcements in polymer matrix. This method aims to
increase the mechanical strength of materials, resulting in
composite materials with wide applicability.
There are numerous materials used as reinforcement of
composites, among them the fibrous one deserve attention.
The fibers are effective means for reinforce due to its low
thickness, tending thus to provide fewer defects that may