The Study on Cure Characteristics and Physical Properties of Ethylene
Propylene Diene Monomer Blended with Recycled Nitrile Gloves
(EPDM/NBRr)
Z.Norhafizah
1, a
, N. Z. Noriman
2, b
, S. T. Sam
3, c
, H. Ismail
4, d
and M. F. Omar
5, e
1
Center of Excellence Geopolymer and Green Technology (CEGeoGTech), School of Materials
Engineering, Universiti Malaysia Perlis (UniMAP), KompleksPengajianJejawi 2, 02600 Arau,
Malaysia
2
School of Materials and Mineral Resources Engineering Campus, Universiti Sains Malaysia, Seri
Ampangan 14300 Nibong Tebal, Seberang Perai Selatan, Penang, Malaysia
a
hafizah909@gmail.com,
b
niknoriman@unimap.edu.my,
c
sam.sunting@gmail.com,
d
hanafi@eng.usm.my,
e
firdausomar@unimap.edu.my
Keywords: EPDM, NBRr, cure characteristics, hardness, crosslink density.
ABSTRACT
Most of the polymeric materials blending together with recycled waste rubber powder attributed to
the economical and processing advantages for product specification. Therefore, the effect of curing
characteristics, hardness and crosslink density of ethylene propylene diene monomer/recycled
acrylonitrile butadiene rubber (EPDM/NBRr) blends were studied. The EPDM/NBRr blends were
prepared at four different compositions (95/5, 85/15, 75/25 and 65/35) with two different sizes (S1:
250-500µm and S2: 3-10cm) of NBRr. Results indicated that the scorch time t
2
, cure time t
90
, and
maximum torque (MH) for both EPDM/NBRr (S1) and EPDM/NBRr (S2) decreased, but the
minimum torque (ML) increased.The increase of NBRr content in EPDM/NBRr leads to the
increase in hardness and consequently decreases the crosslinking density of the blends. The
incorporation of 15phr of S1 recycled NBRr appeared to better overall properties.
INTRODUCTION
Every year, waste rubber generated has given serious environmental issues pollution. The increase
of the waste has attracted some researcher’s interest on how to convert waste and used rubber into
processable form [1]. Blending of two or more different rubber together has been widely
implemented in rubber industry in order to obtain superior properties of final product. It is believed
that blending is an easy and cost effective way to create new combination properties of recycled
rubber waste and the purpose is to improve the physical, mechanical as well as modify processing
characteristics [1, 2]. NBR is a copolymer of butadiene and acrylonitrile which were made from
emulsion process as hot and cold polymer. It is suitable in making some products for automotive
and oil industries such as oil seals, pipe protectors and blowout preventers due to its properties
which is good resistance to nonpolar oils, fats and solvents [2]. Recently, N.Z.Noriman et. al [2] has
reported the study of SBR/vNBR and SBR/rNBR blends. The result obtained that the rNBR
exhibited better properties up to 15 phr compared to vNBR. The interfacial adhesion of rNBR on
SBR matrix was stronger than vNBR/SBR. The study made by N.Suma et. al [3], on the precuring
of EPDM phase in NR/EPDM and butyl phase in NR/Butyl observed that the mechanical properties
in both the phases and in the interface are remarkably improved by precuring. In the present work,
the investigation on the effect of different particle sizes of recycled acrylonitrile butadiene rubber
(NBRr) and blend ratios on curing characteristics, hardness and crosslink density of ethylene
propylene diene monomer/recycled acrylonitrile butadiene rubber (EPDM/NBRr) were carried out.
Applied Mechanics and Materials Vols. 754-755 (2015) pp 120-124 Submitted: 06.01.2015
© (2015) Trans Tech Publications, Switzerland Accepted: 06.01.2015
doi:10.4028/www.scientific.net/AMM.754-755.120
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