Oxid Antioxid Med Sci 2014; 3(2):109-117 ISSN: 2146-8389
http://www.oamsjournal.com 109
ORIGINAL ARTICLE
Hepato-renal damage and oxidative stress associated with
pirimiphos-methyl exposure in male mice
Tarek M. Heikal, Abdel-Tawab H. Mossa, Azza W. Ibrahim, Hala F. Abdel-Hamid
Environmental Toxicology Research Unit (ETRU), Pesticide Chemistry Department,
National Research Center (NRC), Cairo, Egypt
Received April 2, 2014
Accepted May 26, 2014
Published Online June 7, 2014
DOI 10.5455/oams.260514.or.064
Corresponding Author
Tarek Mohamed Heikal
Environmental Toxicology Research
Unit (ETRU), Pesticide Chemistry
Department, National Research Centre,
El-Behoos St., P.O. Box 12622,
Dokki, Cairo, Egypt.
tarekhl@yahoo.com
Key Words
Histopathology;
Kidney function;
Liver function;
Oxidative damage;
Pirimiphos-methyl
Abstract
Objective: For many years, the organophosphorus insecticide pirimiphos-methyl (PM) was used
as a valuable tool against several stored-product insect species. However, the knowledge of its
toxicity for field applicators, manufacturing workers and public health is very limited in
literatures. The present work was therefore undertaken in order to investigate the hepato-renal
toxicity associated with PM exposure in mice.
Method: Mice were divided into five groups of six mice each and administered PM at doses of
0.03 (ADI), 10 (NOAEL), 31.05 (
1
/40 LD50) and 62.11 (
1
/20 LD50) mg/kg body weight in corn oil
for 45 days via oral gavage.
Result: The results revealed that the activities of serum enzymes alkaline phosphatase, alanine
and aspartate aminotransferases, and serum levels of total protein, urea and creatinine were
significantly elevated (by 13-63% of control activity), whereas the level of serum albumin was
significantly reduced (by 15-21%) following administration of 31.05 and 62.11 mg pirimiphos-
methyl/kg body weight. In liver and kidney tissues, level of glutathione and the activity of
superoxide dismutase and catalase enzymes were significantly decreased, while the level of lipid
peroxidation were significantly increased compared to the control group. The lower doses of
(ADI, NOAEL) PM induced insignificant or limited alteration in the above-mentioned
biochemical parameters. Histopathological examination revealed hepato-renal cellular damage in
all tested doses of PM compared to untreated group.
Conclusion: The intensity of the insults in liver and kidney functions as well as oxidative damage
represented by biochemical alterations and histopathological findings were demonstrated in a
dose-dependent manner.
© 2014 GESDAV
INTRODUCTION
Pesticides are ubiquitous in the environment and have
significant economic, environmental and public health
benefits by increasing the food production and
decreasing the vector-borne diseases [1]. Their initial
success was mainly based on their high toxicity, high
biological specificity and rapid environmental
degradation [2]. Organophosphate (OP) compounds are
occasionally used indiscriminately in large amounts
causing environmental pollution [3, 4]. Residual
amounts of OPs including pirimiphos-methyl have been
detected in the soil, water bodies, vegetables, grains
and other foods products [2, 5]. However, the health
effects caused by this occupational exposure are
massive and irreversible in some cases. The widespread
use of OPs and the high rates of food contamination
could leave humans, animals and birds at high risk of
pesticidal toxicity [6, 7].
Organophosphate insecticides represent the most
widely group of pesticides that has been shown to have
toxic effects to non-target organisms [6-9]. They elicit
their extensive toxicities through various mechanisms
and pathways. The primary toxicity associated with
acute exposure to OP insecticides in humans and
animals is the inhibition of acetylcholinesterase
(AChE) enzyme [10]. The inhibition of AChE increases
the availability of acetylcholine which in turn can
stimulate cholinergic receptors producing both
nicotinic and muscarinic effects in the organism such as
muscle contraction and secretion in many glands [11].
However, they also elicit their toxicities via other
mechanisms including cytotoxicity, genotoxicity,
immunotoxicity, delayed polyneuropathy, nephrotoxi-
city, hepatotoxicity, carcinogenicity and reproductive
toxicity [11-19]. Furthermore, OP insecticides induced
toxic effects that probably occur through the generation
of reactive oxygen species (ROS), causing damage to
various membranous components of the cell [20].
Pirimiphos-methyl (PM; O-[2-(Diethylamino)-6-
methylpyrimidin-4-yl] O,O-dimethyl phosphorothioate)
is one of the most commonly used grain protectants
globally. It is an OP compound, with a wide margin of
safety to mammals and a broad spectrum of insecticidal
activity [21]. Arthur et al [22] declared that PM has
been on the market for many years and used as a
valuable tool against several stored-product insect
species. It is rapidly absorbed, metabolized and