Journal of Environmental Protection, 2016, 7, 1592-1604
http://www.scirp.org/journal/jep
ISSN Online: 2152-2219
ISSN Print: 2152-2197
DOI: 10.4236/jep.2016.711131 October 28, 2016
Liming Characteristics of a High-Calcium
Dry Flue Gas Desulfurization By-Product
and a Class-C Fly Ash
Jason R. Burgess-Conforti
1*
, David M. Miller
1
, Kristofor R. Brye
1
,
Lisa S. Wood
1
, Erik D. Pollock
2
1
Department of Crop, Soil, and Environmental Sciences, University of Arkansas, Fayetteville, AR, USA
2
Stable Isotope Laboratory, University of Arkansas, Fayetteville, AR, USA
Abstract
Due to coal’s availability and low cost, coal combustion continues to be the United
States’ primary energy source. However, coal combustion produces large quantities
of waste material. Some coal combustion by-products (CCBs) have chemical and
physical characteristics that make them potentially useful as soil amendments. The
objectives of this study were to characterize a relatively new, high-calcium dry flue
gas desulfurization (DFGD) by-product and compare its agronomic liming potential
to a Class-C fly ash (FA) and reagent-grade calcium carbonate (CaCO
3
). Calcium
carbonate equivalence (CCE), degree of fineness (DOF), and effective neutralizing
value (ENV) for each CCB were determined using standard methods. The CCBs and
CaCO
3
were also incubated with an acidic (~4.5) clay sub-soil at application rates
equivalent to 0, 0.5, 1, and 2 times the soil’s lime requirement and compared to an
unamended control. Soil pH was then measured periodically during a 40-day incuba-
tion. The ENV of 79.4% for the DFGD by-product and 57.3% for the FA were com-
parable to those of commercially available liming materials, but were significantly
lower (P < 0.05) than that of reagent-grade CaCO
3
. After 40 days of incubation at the
0.5× application rate, both CCBs raised the pH of the clay soil to only 5.0, while the
CaCO
3
raised the pH to 6.5. After 40 days at the 1× rate, all three materials had raised
the soil pH to between 6.5 and 7.0, although the FA increased the soil pH more
slowly than did the other two materials. At the 2× rate, both CCBs increased the soil
pH to between 7.5 and 8.0, while the CaCO
3
increased the soil pH to only 7.0. Both
CCBs appear to be useful as soil liming materials, although care should be taken to
avoid over-application, as this may make the soil too alkaline for optimum plant
growth.
How to cite this paper: Burgess-Conforti,
J.R., Miller, D.M., Brye, K.R., Wood, L.S.
and Pollock, E.D. (2016) Liming Characte-
ristics of a High-Calcium Dry Flue Gas
Desulfurization By-Product and a Class-C
Fly Ash. Journal of Environmental Protec-
tion, 7, 1592-1604.
http://dx.doi.org/10.4236/jep.2016.711131
Received: September 19, 2016
Accepted: October 25, 2016
Published: October 28, 2016
Copyright © 2016 by authors and
Scientific Research Publishing Inc.
This work is licensed under the Creative
Commons Attribution International
License (CC BY 4.0).
http://creativecommons.org/licenses/by/4.0/
Open Access