Journal of Food Lipids 12 (2005) 12–22. All Rights Reserved.
12 © Copyright 2005, Blackwell Publishing
TURBIDIMETRIC LIPID ASSAY IN SEED FLOURS
GABI DROCHIOIU
1
Biochemistry Laboratory
Chemistry Faculty
“Al. I. Cuza” University of Iasi
11 Carol I, RO-700506
Iasi, Romania
Received for Publication February 9, 2004
Accepted for Publication September 29, 2004
ABSTRACT
A simple, fast, sensitive and accurate turbidimetric assay of lipids in the
milled seeds was developed. The procedure is based on the extraction of lipids
into acetone followed by their turbidimetric reaction with a 1.5% solution of
sulfosalicylic acid and turbidimetric measurements. The spectral measure-
ment was made at 440 nm against a blank of the reagents. A standard curve
was constructed using raw fat extracted from the species being analyzed. For
analysis of a large number of solvents, the standardization of the turbidimetric
method may be accomplished using Soxhlet values for a few representative
samples. A negative relationship between the hardness of maize particles and
their content of raw fat was observed.
INTRODUCTION
Lipids are very important components of plant seeds that are customarily
determined by solvent extraction in a Soxhlet or a similar apparatus
(Drochioiu 1999). Currently, hexane is most commonly used for oil extraction
from oilseeds. However, due to its toxicity and inflammability, the use of
hexane is strictly regulated. Ethanol is being studied as a possible replacement
for hexane, but ethanol also dissolves certain proteins and carbohydrates in
seeds. Acetone has been shown as a potential solvent for Soxhlet extraction.
Therefore, conventional Soxhlet-type extraction uses flammable solvents and
is time-consuming. Furthermore, the oil content is determined gravimetrically
after solvent evaporation (Hechler et al. 1995). All solvent extraction proce-
dures require several grams of dried sample and consequently the determina-
Blackwell Science, LtdOxford, UKJFLJournal of Food Lipids1065-7258Copyright 2005 by Food & Nutrition Press, Inc., Trumbull, Connecticut.1211222Original ArticleTURBIDIMETRIC LIPID ASSAY IN SEED FLOURSG. DROCHIOIU
1
Corresponding author. TEL: +40-232-201278; FAX: +40-232-201313; EMAIL: gabidr@uaic.ro