Separation and Purification Technology 57 (2007) 25–36 Fouling behaviour, regeneration options and on-line control of biomass-based power plant effluents using microporous ceramic membranes S. Mahesh Kumar a,1 , G.M. Madhu b , Sukumar Roy c, a Department of Biotechnology, R.V. College of Engineering, Bangalore 560059, India b Department of Chemical Engineering, R.V. College of Engineering, Bangalore 560059, India c Ceramic Technological Institute, Bharat Heavy Electricals Limited, Corporate Research & Development, Bangalore 560012, India Received 22 September 2006; received in revised form 14 February 2007; accepted 3 March 2007 Abstract The work presents an on-line filtration treatment for biomass-based power plant effluents using microporous ceramic symmetric membranes with an emphasis on establishment of fouling mechanisms and regeneration options in the process. The work also establishes the relationships among the membrane filterability, quality of permeate and flux to that of the pore size of ceramic membranes. For these purposes, two types of ceramic membrane configurations, i.e., seven-channeled and single-channeled (hollow type) tubes with identical pore size of 1.2 m were selected for the experiments. On the other hand, raw effluents generated by the power plant were first pre-filtered using a 0.5 mm sieve and the resultant filtrate was further used for the present microfiltration trials by varying transmembrane pressure (TMP). Differences in the filterability of the effluents by the two membrane configurations at variable levels of TMP were explained using various membrane-fouling models. The filtration resistances that are acting in series were calculated using Darcy’s and Poiseuille’s law. Establishment of fouling mechanism/s of the membranes and its regeneration by adopting chemical cleaning and backflushing techniques were also an integral part of the study. The results suggest that microfiltration of effluents in a continuous crossflow mode with backflushing in regular intervals offer great advantage over efficiency and effectiveness in monitoring the contaminants in the raw effluents by physical methods. The study hence finds an on-line filtration solution in monitoring biomass-based power plant effluents in a benign way using microporous ceramic membranes. © 2007 Elsevier B.V. All rights reserved. Keywords: Biomass-based power plant effluent; Microfiltration; Ceramic membrane; Fouling; Regeneration; Backflushing 1. Introduction The renewable energy technologies represent a great value in the economy of any nation, but their advantages are hindered by the pollutants they generate in the process that addresses the necessity of integrating the renewable technologies with benign methods of pollution treatment technologies. Biomass- based gasification technology is viewed as an alternative method of producing power out of biomass wastes that in turn, also generates substantial amount of pollutants in the waste efflu- ents in the process. Increasing interest in regulatory bodies to Corresponding author. Tel.: +91 80 22182332; fax: +91 80 23344231. E-mail addresses: mahesh@cpdm.iisc.ernet.in (S. Mahesh Kumar), sroy@bhelepd.com (S. Roy). 1 Present address: Ideas Laboratory, CPDM, IISc, Bangalore 560012, India. curtail waste effluent discharge into aquatic streams has driven the advancement of non-conventional techniques for wastewater reclamation and reuse. Conventional methods of waste effluent treatment include several intermediate steps comprising chemical addition (potash alum, lime and polymers), coagulation, flocculation, sedimen- tation, and disinfection usually with chlorine, etc. All these conventional systems based on the physical and chemical prin- ciples indeed cannot give an absolute guarantee in terms of the separation efficiency and the effluent quality [1]. Strin- gent standards imposed by the regulatory bodies for wastewater discharge limits are not met by the conventional treatment tech- niques [2]. With this scenario, alternative techniques besides the conventional treatments need to be developed to fulfil specific needs of the hour. In the treatment of wastewater effluents, on- line microfiltration has been appearing to be attractive because of its potential to produce high-quality reusable water in one 1383-5866/$ – see front matter © 2007 Elsevier B.V. All rights reserved. doi:10.1016/j.seppur.2007.03.002