Level quantization in the narrow-gap-semiconductor quantum well in a parallel magnetic field V. K. Dugaev and V. I. Litvinov* Chernovtsy Branch of the Institute of Materials Science Problems, National Academy of Sciences of Ukraine, I. Vilde 5, 58001 Chernovtsy, Ukraine W. Dobrowolski Institute of Physics, Polish Academy of Sciences, Al. Lotniko ´w 32/46, 02-668 Warsaw, Poland Received 19 January 2000 An analytical approach is developed for the energy levels in Group-IV–VI narrow-gap semiconductor quantum wells in a parallel magnetic field. Asymptotic closed-form expressions are obtained. Numerical calculations are done for the energy spectrum of the EuS/PbS/EuS quantum well in the magnetic field of an arbitrary strength. The effect of an anisotropy of the electron valleys is also discussed. I. INTRODUCTION The Group-IV–VI narrow-gap-semiconductors find their applications in infrared detectors, lasers, and thermoelectric devices. 1 Further progress in the Group-IV–VI midinfrared optoelectronics is expected from quantum wells QW’s, su- perlattices, and nanoparticles that enable the engineering of their electric and magnetic properties. 2,3 The energy spec- trum of Group-IV–VI-based quantum-size structures is a key element of the device modelling and analysis of the experi- mental data such as photoluminescence and interband magnetoabsorption. 4 In the case of bulk Group-IV–VI semiconductors, the ex- perimental and theoretical study of a spectrum in a magnetic field with detailed numerical calculations have been done. 5,6 At present, known Group-IV–VI QW spectra have been ob- tained only as numerical solutions of Schro ¨ dinger’s equation even in the absence of the magnetic field. 7,3 Numerical cal- culations have also been done for PbTe/Pb 1 -x Sn x Te super- lattices in magnetic fields both parallel and perpendicular to layers. 8 The analytical approaches to an energy spectrum in Group-IV–VI-based QW, with and without perpendicular magnetic field, have been developed in Refs. 9–12. The problem with a perpendicular magnetic field is more easy to analyze because the magnetic quantization concerns the in- plane electron motion and is completely decoupled from size quantization, which concerns a motion in the growth direction. 10 The problem in a parallel field is more complex due to an interference of size- and magnetic-field quantizations—they cannot be separated in any way. The spectrum of Group-IV–VI quantum wells in parallel mag- netic field has been studied analytically in recent works of Ghatak et al. 13,14 within the approach that takes into account the nonparabolicity in a one-band approximation. This ap- proach neglects the electron spin and thus makes impossible to account for the spin-orbit interaction. In this paper we calculate the energy spectrum of a Group-IV–VI QW in parallel magnetic field. The interband coupling and spin-orbit interaction both play a significant role forming the electron spectrum of Group-IV–VI com- pounds. For this reason we use the 4 4 Hamiltonian that is adequate enough to account for all these effects. In the lim- iting cases of weak and strong magnetic field, specified be- low, we obtain closed-form analytical expressions for the field-dependent spectrum. We apply the obtained results to EuS/PbS/EuS QW. This QW is an active region of Group- IV–VI QW lasers, besides, it has the ferromagnetic/ nonmagnetic semiconductor interfaces making it an interest- ing object that combines properties of magnetic and confined systems. 15–18 II. MODEL AND EQUATIONS We consider rectangular quantum well of width 2 L as shown in Fig. 1. In the case of Group-IV-VI type semicon- ductors, the Hamiltonian of electrons in parallel magnetic field with H along axis x is a Dirac-like type 1 we take units with =1) H = c z v k -eA / c v k -eA / c - v z , 1 where c ( z ) = 0 for | z | L , and c ( z ) = 1 for | z | L , while v ( z ) = 0 for | z | L , and v ( z ) = 2 for | z | L Fig. 1, v is the band-coupling parameter, A is the vector poten FIG. 1. The model of quantum well. PHYSICAL REVIEW B 15 JULY 2000-I VOLUME 62, NUMBER 3 PRB 62 0163-1829/2000/623/19057/$15.00 1905 ©2000 The American Physical Society