© Copyright by International OCSCO World Press. All rights reserved. 2007
VOLUME 24
ISSUE 2
October
2007
Research paper 35
of Achievements in Materials
and Manufacturing Engineering
of Achievements in Materials
and Manufacturing Engineering
Dispersion – strengthened
nanocrystalline copper
J.P. Stobrawa
a,b,
*, Z.M. Rdzawski
a,b
a
Division of Materials Processing Technology, Management and Computer Techniques
in Materials Science, Institute of Engineering Materials and Biomaterials,
Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
b
Non-Ferrous Metals Institute, ul. Sowińskiego 5, 44-100 Gliwice, Poland
* Corresponding author: E-mail address: jerzys@amme.com
Received 23.03.2007; published in revised form 01.10.2007
Materials
AbstrAct
Purpose: The aim of this work was to investigate microstructure, mechanical properties and deformation
behaviour of dispersion strengthened nanocrystalline copper produced by powder metallurgy techniques.
Design/methodology/approach: Tests were performed with the Cu, Cu-tungsten carbide and Cu-yttria
micro-composites containing up to 3 wt.% of a strengthening particles. The mechanical properties, initial
nanocrystalline structures and their evolution during deformation processes were investigated.
Findings: The obtained strengthening effect have been discussed based on the existing theories related to
strengthening of nanocrystalline materials. The studies have shown the importance of “flows” existing in the
consolidated materials and sintered materials such as pores or regions of poor powder particle joining which
significantly deteriorate mechanical properties of micro-composites produced by powder metallurgy.
Research limitations/implications: The powder metallurgy techniques make it possible to obtain copper-based
bulk materials by means of milling input powders in the planetary ball, followed by compacting and sintering.
Additional operations of hot extrusion are also often used. There is some threat, however, that during high-
temperature processing or using these materials at elevated or high temperatures this nanometric structure may
become unstable.
Practical implications: A growing trend to use new copper-based functional materials is observed recently
world-wide. Within this group of materials particular attention is drawn to those with nanometric grain size of a
copper matrix, which exhibit higher mechanical properties than microcrystalline copper.
Originality/value: The paper contributes to the mechanical properties of dispersion strengthened (with tungsten
carbide and yttria) nanocrystalline copper and to the elucidation of deformation behaviour of these materials
with high porosity.
Keywords: Nanomaterials; Mechanical properties; Electron microscopy; Metallography; Powder metallurgy
1. Introduction
Dispersion – strengthened copper (DSC) is a group of
functional and structural materials. They could be used as
electrical contact materials in relays, contactors, switches, circuit
breaks, resistance–welding tips, continuous casting moulds and so
on, where combination of high electrical or/and thermal
conductivity with high strength at room and elevated temperatures
is required.
A growing trend to use such functional materials is recently
observed world-wide. Within this group of materials particular
attention is drawn to those with nanometric grain size of a copper
matrix, which exhibit higher mechanical properties than
microcrystalline copper.
1. Introduction