1
Supporting Information
Enhancement of quantum yield of LaPO
4
:Ce
3+
:Tb
3+
nanocrystals by carbon nanotube induced suppression of the
1-dimensional growth
Jie Fang,
a,b
Yanglong Guo,
a
Guanzhong Lu,*
a
Colin L. Raston
b
and K. Swaminathan
Iyer*
b
a
Key Laboratory for Advanced Materials and Research Institute of Industrial Catalysis, East
China University of Science and Technology, Shanghai 200237, P. R. China. E-mail:
gzhlu@ecust.edu.cn
b
Centre for Strategic Nano-Fabrication, School of Biomedical, Biomolecular and Chemical
Sciences The University of Western Australia, Crawley, WA 6009, Australia. E-mail:
swaminatha.iyer@uwa.edu.au
Experimental
All chemicals utilized in the synthesis were purchased from Sigma-Aldrich without
further purification. High purity single wall carbon nanotubes (SWCNTs) was
purchased from Chengdu Organic Chemicals Co. Ltd., Chinese Academy of Sciences.
The SWCNT was functionalized using a literature method for producing water
soluble SWCNTs. Briefly, the SWCNT was functionalized by treating 10 mg in acid
mixture of 10ml of concentrated HNO
3
and 10 ml of concentrated H
2
SO
4
followed by
heated at 80°C for 2.5 hours.
1
The SWCNTs were purified by multiple washes with
water to neutral pH.
LaPO
4
:Ce
3+
:Tb
3+
and LaPO
4
:Ce
3+
:Tb
3+
@SWCNT were prepared with the
literature method using a previously described rotating tube microfluidic platform to
aid room temperature crystallization of well defined nanoparticles.
2
In a typical
synthesis of LaPO
4
:Ce
3+
:Tb
3+
, 1 mM LnCl
3
solution (a mixture of 40% LaCl
3
, 45%
CeCl
3
and 15% TbCl
3
with a total concentration of 1 mM) and 1mM NaH
2
PO
4
were
fed from two feed jets into the rotating tube continuously at a feed rate of 60 ml/min,
and rotational speed of the tube was fixed at 1700 rpm. The products were collected at
Supplementary Material (ESI) for Dalton Transactions
This journal is © the Royal Society of Chemistry 2011