ELSEVIER Precambrian Research 84 (1997) 163-180
Pre(umbriun
Resenrth
Geochemistry and petrology of recycled orogen-derived sediments:
a case study from Upper Precambrian siliciclastic rocks of the
Central Iberian Zone, Iberian Massif, Spain
J.M. Ugidos *, I. Armenteros, P. Barba, M.I. Valladares, J.R. Colmenero
Departamento de Geologia, Facultad de Ciencias, Universidad de Salamanca, 37008 Salamanca, Spain
Received 3 January 1997; accepted 1 May 1997
Abstract
Two areas of Upper Precambrian siliciclastic rocks separated from each other by 150 km were selected in the
Central Iberian Zone (CIZ) for a petrological and geochemical study. The petrology of the coarser-grained rocks
indicates the absence or scarcity of igneous clasts, the presence of extrabasinal and intrabasinal clasts and homogeneous
features of sandstones ranging from very-fine to fine-grained. The modal data of these rocks plot close to the Qt-L
and Qm-Lt sides of QtFL and QmFLt triangular diagrams, suggesting provenance from a recycled orogen.
The geochemical data on the shales and sandstones from the two areas studied are very uniform. Both groups of
rock show similar ranges of relevant major element ratios such as A1203/TiO2 (17.46-21.51; 17.46-21.34, for shale
and sandstone, respectively), A1203/FeOx (2.40-3.79; 2.18 3.33) and FeOx/FeOx+MgO (0.71-0.77; 0.68-0.76),
together with parallel average rare earth element (REE) patterns and similar values for some key trace element ratios
(La/Th, Th/Yb, Th/U, Zr/Hf, Sm/Nd and Cr/Sc). Other trace element ratios (La/Sc, Th/Sc, Cr/Th and Cr/Zr) are
uniform in the shales group and also in the sandstones group, although minor differences become apparent when
both groups are compared. These differences are probably related to the quartz dilution effect affecting the relative
abundance of phyllosilicates in these rocks and, indirectly, the Sc and Cr contents, given their covariations with
Al203. The Zr/Yb, Zr/Y and Zr/Th ratios of the shales are uniform; the sandstones show higher and more variable
values, and there is no correlation between Zr abundance and any of these ratios in the shales or sandstones. Together
with the parallel REE patterns shown by both groups of rock, these results suggest the absence of heavy mineral
fractionation during the transport of detrital material and/or the relative importance of other minerals, probably
phyllosilicates, in the control of Yb, Y and Th abundances.
Apparently, all the groups of rocks show a remarkable geochemical homogeneity despite the distance between the
sampling areas. Thus, the petrological and chemical data are consistent and point to a very extensive, homogeneous
and stable source region as the most plausible contributor to the Upper Precambrian siliciclastic rocks in the CIZ.
The possible relationship between this zone and N Gondwana is also discussed. © 1997 Elsevier Science B.V.
Keywords: Geochemistry; Iberian Massif; Petrology; Siliciclastic rocks; Spain; Upper Proterozoic
* Corresponding author. Fax: 003423294514.
0301-9268/97/$17.00 © 1997 Elsevier Science B.V. All rights reserved.
PH S0301-9268 (97)00023-5