African Journal of Pharmacy and Pharmacology Vol. 6(25), pp. 1854-1859, 8 July, 2012
Available online at http://www.academicjournals.org/AJPP
DOI: 10.5897/AJPP12.277
ISSN 1996-0816 ©2012 Academic Journals
Full Length Research Paper
Bioactivity potential of extracts from ascidian
Lissoclinum fragile
N. Sri Kumaran
1
, S. Bragadeeswaran
1
*, T. Balasubramanian
1
and V.K Meenakshi
2
1
Centre of Advanced Study in Marine Biology, Faculty of Marine Science, Annamalai University, Parangipettai - 608 502,
India.
2
A. P. C. Mahalakshmi College for Women, Tuticorin - 628 016, Tamil Nadu, India.
Accepted 4 June, 2012
Ascidians are marine biofouling animals with a proven ability to synthesis bioactive substances. This
study investigated the bioactive potential of ascidian Lissoclinum fragile, found in the coastal waters of
Tuticorin Southeast coast of India. Freshly collected ascidian soaked in methanol for five days and
filtered through filter paper. The solvent was concentrated by rotary evaporator which reduced the
pressure to give a dark brown gummy mass. The collected gummy mass was separately extracted
successively with acetone, n-butanol, chloroform, ethyl acetate and dichloromethane. These extracts
were used for antimicrobial, heamolytic and cytotoxic assays. In antibacterial assay bacterial pathogen,
S. typhi exhibit high zone of inhibition (14.1 ± 0.01 mm) against dichloromethane extract. In antifungal
assay, fungal pathogen Penicillium species showed high zone of inhibition (12.3 ± 0.07 mm) against n-
butanol extract. In haemolytic assay, n-butanol extract showed high heamolytic activity in chicken
erythrocytes (64 HU), goat erythrocytes (16 HU) and cow erythrocytes (16 HU). In cytotoxic activity, n-
butanol extract exhibited high LC
50
value (97 μg/ml) against brine shrimps. These results indicate that
the ascidian L. fragile has remarkable antimicrobial, haemolytic, and cytotoxic activities.
Key words: Ascidian, Lissoclinum fragile, haemolytic and cytotoxic activities, antimicrobial.
INTRODUCTION
The biodiversity of the marine environment constitute a
practically unlimited resource of active substances for the
development of natural bioactive products. Of the natural
products isolated from marine organisms, less than 1%
have been examined for pharmacological activities
(Fusetani, 2002). Biological activities that have been
frequently observed in marine invertebrate crude extracts
include antibiosis against human microbial pathogens,
marine microorganisms, and cytotoxicity (Mayer et al.,
2007). Many marine invertebrate secondary metabolites
have presented both antibiotic and cytotoxic activities as
a result of increased research into these bioassays for
new drugs (Newman et al., 2003). A large proportion of
natural compounds that have been extracted from marine
*Corresponding author. E-mail: drpragathi@gmail.com. Tel: +91
4144 243223/269 or +91 9894823364.
invertebrates, especially sponges, ascidians, bryozoans,
of biologically active compounds, especially amino acid
derived nitrogenous secondary metabolites (Rinehart,
2000) and antimicrobial, antiviral, and anti-inflammatory
compounds (Davidson, 1993). Although, research on
bioactive compounds from ascidians was recently
initiated, the first marine natural product entering human
clinical trials, Didemnin B, is an ascidian metabolite.
Several ascidian compounds in anticancer preclinical or
clinical trials include the tetrahydroisoquinolone alkaloid,
‘Ecteinascidin 743’ from Ecteinascidia turbinata; cyclic
depsipeptides, ‘Dehydrodidemnin B’ and ‘Didemnin B’
from Trididemnum solidum; cyclic peptide, ‘Vitilevuamide’
from Didemnin cuculiferum; and ‘Diazonamide’, from
Diazona angulata (Jain et al., 2008). Potential ascidians
need to be explored for pharmaceutical use, and a broad
based screening of ascidians for bioactive compounds is
necessary. This study evaluates the biological properties
from the biofouling ascidian Lissoclinum fragile, collected