[Barde et. al., Vol.4 (Iss.12: SE): December, 2017] ISSN: 2454-1907
[New Frontiers in Science: A Paradigm Shift to Policy Planning] DOI: 10.5281/zenodo.1163777
Http://www.ijetmr.com©International Journal of Engineering Technologies and Management Research [98]
VISIBLE LIGHT IRRADIATED PHOTCATALYTIC DEGRADATION OF
ORANGE II DYE IN PRESENCE OF ZnO NANOPARTICLES
Veer Singh Barde
*1
, Brijesh Pare
2
, Shivpriya Pare
3
, Satish Piplode
4
*1, 2, 3, 4
Laboratory of Photocatalysis, Department of Chemistry, Goverment Madhav Science P G
College, (af. Vikram University), Ujjain, MP 456 010, India
Abstract:
Zinc oxide nanoparticles were obtained by chemical precipitation method using zinc nitrate
and aqueous solution of sodium hydroxide as precursors. The ZnO nanoparticles exhibited
excellent photocatalytic activity for Orange-II dye degradation under visible light irradiation.
ZnO nanoparticles are easy to recover and can be used upto three times without loss of
degradation activity. We observed that Fenton reagent showed good activity for Orange II dye
decolourization and degradation. Photocatalytic degradation of Orange II dye using
H
2
O
2
/Fe
3+
has also been studied and optimum conditions for the decolourization and
degradation of dye has been established.
Keywords: ZnO Nanoparticles; Orange-II Dye; Photo-catalytic Degradation; Visible Light.
Cite This Article: Veer Singh Barde, Brijesh Pare, Shivpriya Pare, and Satish Piplode. (2017).
“VISIBLE LIGHT IRRADIATED PHOTCATALYTIC DEGRADATION OF ORANGE II
DYE IN PRESENCE OF ZnO NANOPARTICLES.” International Journal of Engineering
Technologies and Management Research, 4(12: SE), 98-103. DOI: 10.5281/zenodo.1163777.
1. Introduction
In the textile industries, during manufacturing and processing operations large amount of dyes
are lost to the effluents and these colored dye effluents create severe environmental pollution
issues by discharging toxic and potential carcinogenic substances into the aquatic sources.
1
Therefore, some new treatment methods are required for the removal of persistent dye molecules
into converting them in harmless compounds in water.
2-5
These effluents generated from these
industries when contains considerable amounts of dyes causes coloration of water and poses a
threat to aquatic life as well.
6
Moreover, their existence in drinking water constitutes a potential
human health hazard. Hence, it is crucial to eliminate these dyes from water.
7-8
Advanced oxidation processes (AOPs) have been popular for degradation of organic pollutants in
recent years, due to its effectiveness and environmentally safe nature. These processes are based
on the production of
.
OH radicals and for degradation they attacks on most of the organic
molecules without any specific selectively.
9-10
Photo-catalysis using semiconductor has been widely studied for its potential application in
environmental protection and solar energy transformation. In the past few years many catalysts