International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 08 Issue: 11 | Nov 2021 www.irjet.net p-ISSN: 2395-0072
© 2021, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 1606
Analysis the Amounts of Heavy Metals and Trace Elements in Water of
Different Sources of Ranchi city by using ICP-OES Technique
Vikash Kumar
1
, Ashok K Acharya
2
1
M.Sc. Scholar, Dept. of Chemistry, Dr Shyama Prasad Mukherjee University Ranchi, Jharkhand, India
2
Assistant Professor, Dept of Chemistry, Dr Shyama Prasad Mukherjee University Ranchi, Jharkhand, India
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Abstract – The study was aimed to analyze the
concentration of metals including heavy metals and trace
elements in the water of four different small water bodies or
sources including two pond, one lake and one river around the
Ranchi city. The metals or trace elements such as Ag, Al, B, Bi,
Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb and Zn were
analyzed by using Inductively Coupled Plasma- Optical
Emission Spectroscopy technique. The results indicated that
the concentration of approximately all the metals, heavy
metals and trace elements in these waterbodies were found
within the maximum permissible limit set by IS:2296, EPA and
WHO for surface water quality standard. Higher
concentrations of Al in Lake of Chamber, Bi and Mn in Jumar
river than other sites, were reported.
Key Words: Heavy Metal Analysis, Trace Elements, ICP-
OES Technique, Water Analysis, Emission Spectroscopy,
Ranchi City.
1. INTRODUCTION
India is a country with a diverse landscape and rivers. There
are 14 major rivers and other freshwater bodies, both large
and small. Water, the universal solvent, has the property of
dissolving most compounds due to its high dielectric
constant, but an excess of these chemicals causes water
pollution, including heavy metal and trace element
contamination. The discharge of effluents from industries,
home activities, and soil contamination from adjacent
dumping sites and agricultural drainage, damage the water
bodies based on water quality prospective[1].
Jharkhand, one of the states in eastern part of India, is
known to have minerals rich state globally. Jharkhand is a
wonderful land with enormous potential and a plethora of
other natural resources. The state covers a geographical area
of 79,714 km
2
, has 29.61 percent forest land, and holds
roughly 40% of India's total mineral resources, as per data
provided by Department of Mines and Geology, Government
of Jharkhand [2].
Due to being one of the minerals rich State of Indian
Republic, there are various metals including heavy metal and
trace element contaminations in water including ground and
surface water, soil and air as well. The presence of these
types of heavy and trace metals/elements in water bodies
causes serious impact on human health as they enter in
human body directly through drinking or indirectly through
the consumption of aquatic products (viz. fishes, etc.)
obtained from these water bodies and agricultural products,
irrigated with water from these sources. As per explained by
[3] (G. S. David and I. A. Isangedighi, 2019), heavy metals
transferred into the marine environment may be absorbed
into the marine food chain and eventually reach human
consumers via aquatic transport, causing a number of major
health risks.
Heavy metals are described as "any metallic element with a
relatively high density (mass/volume) that is poisonous
even at extremely low concentrations; or a class of metals
and metalloids having an atomic density greater than 4g/cm
3
or 5 times that of water”[4]. The body cannot detoxify
certain metals because they are stable. In the acidic medium
of the stomach, these metals are turned to their stable
oxidation states such as Cd
2+
, Mg
2+
Zn
2+
, Pb
2+
, Ni
2+
, Cr
3+
, Cr
6+
,
etc and unite with the sulfhydryl groups of biomolecule of
human body such as proteins, lipids, DNA and enzymes to
establish strong and stable chemical bonds[5]. Protein
denaturation (Hg, Pb and Cd), Inhibition of cell division (Hg,
Pb, Cd and Ni), Cell membrane disruption (Hg, Pb, Zn, Ni, Cu
and Cd), Inhibition of enzyme activity (Hg, Pb, Zn, Ni, Cu and
Cd) and transcription inhibition, are the main toxicity
mechanism affecting the microorganisms. Heavy metals
enter the environment through both natural and human-
caused sources. Earth’s crust natural weathering, sewage
effluents, soil erosion, urban runoff, industrial discharge,
pest or disease control agents applied to plants, and air
pollution fallout are examples of such sources. Heavy metal
contamination of the aquatic environment has become a
global issue in recent years, owing to their indestructibility
and the fact that most of them have hazardous effects on
species[6].
As per being one of the main objectives of this instrumental
analysis, there are some heavy metals and trace elements
whose concentration in water bodies, were analyzed by
using Inductively Coupled Plasma- Optical Emission
Spectrometry (ICP-OES) technique. These metal and
elements are- Silver (Ag), Aluminum (Al), Boron (B),
Chromium (Cr), Copper (Cu), Iron (Fe), Potassium(K),
Magnesium (Mg), Manganese (Mn), Calcium (Ca), Cadmium