Water-gas shift: characterization and testing of nanoscale YSZ supported Pt catalysts Michela Martinelli 1,2 , Gary Jacobs 1 , Uschi M. Graham 1 , Wilson D. Shafer 1 , Donald C. Cronauer 3 , A. Jeremy Kropf 3 , Christopher L. Marshall 3 , Syed Khalid 4 , Carlo G. Visconti 2 , Luca Lietti 2 , Burtron H. Davis 1,* 1 Center for Applied Energy Research, University of Kentucky, 2540 Research Park Dr., Lexington, KY 40511, USA 2 Politecnico di Milano, Dipartimento di Energia, Piazza Leonardo da Vinci, Milano 20133, Italy 3 Argonne National Laboratory, Argonne, IL 60439, USA 4 National Synchrotron Light Source, Brookhaven National Laboratory, Brookhaven Ave, Upton, NY 11973, USA *Corresponding author: burtron.davis@uky.edu ; 859-257-0251 Abstract Nano-scale Y-doped zirconium oxide materials were prepared with high surface areas (150-200 m 2 /g) and small nano-crystallites (< 8 nm). A combination of XANES and EXAFS was used to show that ZrO 2 exhibited the tetragonal phase, while the Zr 0.5 Y 0.5 O 1.75 support displayed the cubic phase. A comparison with undoped zirconia suggests that the Zr 0.9 Y 0.1 O 1.95 support was tetragonal in structure. A slight increase in d-spacing observed in HR-TEM for the Zr 0.9 Y 0.1 O 1.95 support relative to undoped ZrO 2 , along with a shift to lower 2θ in XRD, provide evidence that Y-doping caused macrostrain. STEM imaging confirmed that the Pt clusters ranged from 0.5 to 2 nm over all three supports. Catalyst reducibility was explored by H 2 -TPR, XANES at the Zr K-edge, and TPR-XANES at the Pt L III edge. A higher concentration of surface defects for the 0.5%Pt/Zr 0.9 Y 0.1 O 1.95 catalyst relative to 0.5%Pt/ZrO 2 was confirmed by DRIFTS of adsorbed CO, while a greater surface mobility of surface formate was suggested based on forward formate decomposition experiments in steam. The Y-doped Pt promoted catalysts displayed higher water-gas-shift activity relative to the 0.5%Pt/ZrO 2 catalyst when the Y content was at or below 50%, with the best catalyst being 0.5%Pt/Zr 0.9 Y 0.1 O 1.95 . © 2015. This manuscript version is made available under the Elsevier user license http://www.elsevier.com/open-access/userlicense/1.0/