© Copyright by International OCSCO World Press. All rights reserved. 2007
VOLUME 24
ISSUE 2
October
2007
Research paper 11
of Achievements in Materials
and Manufacturing Engineering
of Achievements in Materials
and Manufacturing Engineering
Sinter-hardening process applicable
to stainless steels
L.A. Dobrzański
a,
*, Z. Brytan
a
, M. Rosso
b
a
Division of Materials Processing Technology, Management and Computer Techniques
in Materials Science, Institute of Engineering Materials and Biomaterials,
Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
b
Politecnico di Torino, Alessandria Campus, Viale T.Michel 5, 15100, Italy
* Corresponding author: E-mail address: leszek.dobrzanski@polsl.pl
Received 12.04.2007; published in revised form 01.10.2007
Manufacturing and processing
AbstrAct
Purpose: of this paper was to describe sintered duplex stainless steels manufactured in sinter-hardening process
and its usability in field of stainless steels.
Design/methodology/approach: In presented study duplex stainless steels were obtained through powder
metallurgy starting from austenitic, ferritic base powders by controlled addition of alloying elements, such as Cr, Ni,
Mo and Cu. In the studies apart from the preparation of mixes, Schaeffler’s diagram was taken into consideration.
Prepared mixes have been compacted at 800 MPa and sintered in a vacuum furnace with argon backfilling at
temperatures from 1200°C to 1285°C for 0.5, 1 and 2 h. After sintering different cooling cycles were applied using
nitrogen under pressure from 0.6 MPa to 0.002 MPa in argon atmosphere. Produced duplex stainless steels have
been studied by scanning and optical microscopy and EDS chemical analysis of microstructure components.
Findings: Obtained microstructure and mechanical properties of sintered duplex stainless steel strictly depend
on the density and the pore morphology present in the microstructure and especially on cooling rate directly
from sintering temperature in sinter-hardening process. The lowest cooling rate - applied gas pressure, the
mechanical properties and corrosion resistance decrease due to precipitation of sigma phase. Proper bi-physic
microstructure was obtained using nitrogen under pressure of 0.6 and 0.2 MPa.
Research limitations/implications: Applied fast cooling rate seems to be a good compromise for mechanical
properties and obtained microstructures, nevertheless further tests should be carried out in order to examine its
influence on corrosion properties.
Originality/value: The utilization of sinter-hardening process combined with use of elemental powders added
to a stainless steel base powder shows its potentialities in terms of good microstructural homogeneity and
especially working with cycles possible to introduce in industrial practice.
Keywords: Sintering; Sinter-hardening; Powder metallurgy; Duplex stainless steel
1. Introduction
Application of powder metallurgy as a highly cost effective
and high performance and possibility of manufacturing products
with dimensional stability and shape reproducibility, created
chances to manufacture duplex stainless steels witch controlled
mechanical properties and corrosion resistance. Stainless steels
made by powder metallurgy mainly single-phase stainless steels,
austenitic and ferritic with desired mechanical properties – ferritic
stainless steels and high corrosion resistance – austenitic one, for
many years have stable position on market of sintered
components. The powder metallurgy stainless steels, especially
ferritic grades, have found applications in mounting brackets for
the rear view mirrors, the tone wheels for the antilock brake
systems and also in automotive exhaust applications like exhaust
flanges and mounting unit of HEGOS. The automotive market
introduces newly designed sintered parts in large amounts in
1. Introduction