Removal of heavy metals using Amine crosslinked
Reduced Graphene Oxide
Cadiam Mohan Babu
1,2
, Rajangam Vinodh
1,2
, Aziz Abidov
1,2
, Rramaswamy
Ravikumar
1,2
, Mei Mei Peng
1,2
, Wang Seog Cha
2,3
and Hyun-Tae Jang
1,2
1
Department of Chemical Engineering, Hanseo University, Seosan 360-706,
South Korea
2
Korea Carbon Capture and Sequestration R and D Centre, 360 Daegok-ri, Haemi-myun,
Seosan-si 356 706, Chungcheongnam-do, South Korea
3
School of Civil and Environmental Engineering, Kunsan National University, Kunsan 573-
701, South Korea
E-mail: htjang@hanseo.ac.kr; Fax: +82-041-688-4143; Tel: +82-041-660-1423
Abstract. Graphene oxide was synthesized by modified Hummers method and
then reduced with hydrazine hydrate to obtain reduced graphene oxide. (3-
aminopropyl)trimethoxysilane used as a precursor for amine functionalized
reduced graphene oxide. The amine functionalized nanoparticles were
characterized using FT-IR, TGA, Raman, N
2
sorption, SEM and TEM
techniques. The surface area was found to be 346 m
2
/g due to functionalization
of amine over reduced graphene oxide. The amine functionalized nanoparticles
were used as adsorbent for the removal of heavy metals from aqueous solution.
The adsorption of heavy metal was high for the reduced graphene oxide
nanocomposites when compared to bare amine functionalized nanoparticles.
The maximum adsorption reached within fifteen minutes.
Keywords: Reduced Graphene Oxide, Amine Functionalized, Heavy metals
and Nanocomposites.
1 Introduction
Water is one of the basic needs required for sustaining healthy life. It is therefore not
a surprise that water has occupied an important position in the activities of mankind.
With the development of industrialization and urbanization, water utilization has
increased double every fifteen years [1]. Due to the industrialization the water is
contaminated by various contaminants in that heavy metal plays a vital role. A heavy
metal is any metal or metalloid of environmental concern. The word specified with
reference to the harmful effects of lead, mercury and cadmium, all of which are
denser than iron. It has also been applied to other toxic metal, or metalloid such as
arsenic. Heavy metals “can bind to vital cellular components, such as structural
proteins, nucleic acids and enzymes, and interfere with their routine functioning”.
Heavy metals are very dangerous, unlike organic contaminants, they are non-
biodegradable and making great impact and threat to the ecological environment and
Advanced Science and Technology Letters
Vol.120 (GST 2015), pp.430-433
http://dx.doi.org/10.14257/astl.2015.120.83
ISSN: 2287-1233 ASTL
Copyright © 2015 SERSC