Indian J. Phys. 84 (10), 1341-1346 (2010)
© 2010 IACS
Optical and electrical properties of p-type transparent
conducting CuAlO
2
thin film synthesized by reactive
radio frequency magnetron sputtering technique
B Saha, R Thapa, S Jana and K K Chattopadhyay
*
Thin Film and Nanoscience Laboratory,
Department of Physics, Jadavpur University, Kolkata-700 032, India
E-mail : kalyan_chattopadhyay@yahoo.com
Abstract : Thin films of p-type transparent conducting CuAlO
2
have been synthesized through reactive radio
frequency magnetron sputtering on silicon and glass substrates at substrate temperature 300
0
C. Reactive sputtering
of a target fabricated from Cu and Al powder (1:1.5) was performed in Ar+O
2
atmosphere. The deposition parameters
were optimized to obtain phase pure, good quality CuAlO
2
thin films. The films were characterized by studying
their structural, morphological, optical and electrical properties.
Keywords : Sputtering; electrical conductivity; optical properties
PACS Nos. : 81.15.Cd; 73.50.-h; 78.66.-w
1. Introduction
In recent years, extensive studies have been carried out on transparent conducting oxide
semiconductor materials of both p- and n-type. It has been found that there are many
oxide materials like ZnO [1-3], CdO [4, 5], SnO
2
[6, 7] etc. which can serve as a good n-
type TCO material. Many efforts have been focused on the search for a suitable p-type
transparent conducting oxide (TCO) material for thin film applications. Different materials
like CuO [8, 9], NiO [10, 11] etc. show p-type conductivity but do not have enough
technical advantages either because of low conductivity or for not having sufficiently
large band gap to become transparent in the visible region. CuAlO
2
is one of the ideal
p-type materials which can be employed to prepare thin films with excellent technical
ability. Consequently CuAlO
2
thin films can be used in various applications such as in
solar cells [12], light emitting diodes, photo transistors etc. Different deposition techniques
*Corresponding Author