International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 10 (2018) pp. 7954-7958
© Research India Publications. http://www.ripublication.com
7954
Influencing of Clay and Binder Content on Compression Strength of Soft
Soil Stabilized by Geopolymer Based Fly Ash
Son Hoang Trinh
1
, Quynh Anh Thi Bui
2
1
Department of Structure and Construction Material, University of Transport Technology, 54 Trieu Khuc, Thanh Xuan, Hanoi, Vietnam.
2
Department of Geotechnical Engineering, University of Transport Technology, 54 Trieu Khuc, Thanh Xuan, Hanoi, Vietnam.
Abstract
Soil stabilization with binder now is a common method for
treating weak soil. In this study, soft soil was mixed with
geopolymer based fly ash binder to improve strength and to be
environmentally friendly. Clay soil was mixed with sand to
change the clay content by 24.8%, 20.4%, 14.3%, 10.2%,
6.1% and combined with fly ash geopolymer binders at the
rates of 5%, 10%, 15%, 20%. Geopolymer based fly ash
binder include activated alkaline solution (AAS)
Na2SiO3/NaOH = 2, AAS/fly ash = 0.5. Compressive strength
of soil specimens stabilized by geopolymer depends on
several factors such as clay content, and geopolymer binders.
The results show that clay and geopolymer binder content
play an important role in the development and formation of
strength of geopolymer-soil.
Keywords: soil stabilization, geopolymer, compressive
strength, clay.
INTRODUCTION
Soil stabilization is a change of one or more properties of the
soil to ensure stability during the construction works and
service life. There are two basic methods for soil stabilization:
mechanical and chemical methods. The mechanical method
based on reducing the porosity, increasing the particle size in
the soil. Also, chemical methods based on chemical reactions
between soil and binders [2], [3]. Many countries around the
world have used chemical methods to improve the soil with
organic and inorganic binders in the construction of roads,
airports, dams...with significant economic - technical
efficiency. The main purpose of soil stabilization by binder is
to improve adhesion of soil particles prior to change effects of
clay on soil properties such as improving permeability,
compressive strength and reduce erosion [4]. Certainly, in the
soil, clay particles play a very important role in the formation
of mechanical properties, specially permeability and
compressibility. They bond coarse particles in the soil
together. On the other hand, clay is a component that often
changes its properties by moisture. Thereby it has a great
effect on the strength and durability of soil. The additives or
chemical binder to mechanical properties of soil is to
fundamentally change water stability of clay [5].
The term "geopolymer" (geopolymer binder) was first
introduced to the world in 1978 by French researcher, Joseph
Davidovits. Geopolymer is a type of binder obtained by
combining inorganic materials rich of alumosilica (Si-Al)
such as metakaoline, fly ash, husk ash, blast furnace slag with
chemical compounds called “activated alkaline solution” such
as NaOH (or KOH) and Na2SiO3 (or K2SiO3) [6], [7]. The
reaction is inorganic polymerization process (also called
mineral polymerization). The structure of this geopolymer is
"poly-sialate" Si-Al-O. Polysialate chain and ring structure
consist of three-dimensional tetrahedrons structures of (SiO4)
4-
and (AlO4)
5-
by sharing oxygen atoms to replace aluminate
(aluminum oxide) with difference degree in all directions.
Cations may be any alkaline to neutralize the negative ion of
(AlO4)
5-
to form monomers in the polysialate network [1]:
Mn {- (SiO2)z-AlO2}n.wH2O
Where:
"M" is a cation or alkaline element (positive ion);
"n" is the degree of polymerization;
"-" indicates the presence of a bond;
"z" is the replacement degree for aluminate (1,2,3 or
higher, up to 32).
Different dgree of aluminate replacement will produce
different geopolymer molecular structures. The Si: Al ratio in
the polysialate structure determines the properties of the
geopolymer binder. The chemical reaction that forms the
geopolymer can be summarize the following steps [1], [7]:
Dissolve the Si and Al molecules in the alumosilica material
by the hydroxide ions in the activated alkaline solution;
Repositioning ions in solution to form monomers; Combining
the monomers through the polymerization reaction to form the
geopolymer structure.
Geopolymers can expose good mechanical properties such as
low permeability, high compressive strength, high durability
can be achieved if combined at certain conditions [7].
EXPERIMENTAL STUDY
Sample preparation material
Soil
Soil has unconfined compressive strength of 0.04MPa, unit
weight 16.68kg/m
3
, moisture 55.2%. The soil was milled
before conduct study. The percent finer and chemical
composition are presented in Table 1 and Table 2,
respectively.