Tapan Kumar Maity et al., Int. J. Res. Pharm. Sci., 2021, 12(2), 1648-1658
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Synthesis, characterization, molecular docking and in vitro anticancer
activity of 3-(4-methoxyphenyl)-5-substituted phenyl-2-pyrazoline-1-
carbothioamide
Benupani Sahu
1
, Rajapandi R.
2
, Avik Maji
1
, Abhik Paul
1
, Tanushree Singha
1
, Tapan Kumar Maity
*1
1
Division of Pharmaceutical Chemistry, Department of Pharmaceutical Technology, Jadavpur
University, Kolkata – 700032, West Bengal, India
2
Department of Pharmaceutical Chemistry, Arulmigu Kalasalingam College of Pharmacy, Krishnan
Koil – 626126, Tamilnadu, India
Article History:
Received on: 15 Mar 2020
Revised on: 01 Apr 2021
Accepted on: 12 Apr 2021
Keywords:
Anticancer,
Molecular docking,
Pyrazoline,
SRB Assay and Molegro
Virtual Docker
AćĘęėĆĈę
In the present study, eight numbers of new 3- (4-methoxy phenyl)-5-
substituted phenyl-2-pyrazoline-1-carbothioamide (5a-h) have been synthe-
sized from 1- (4-methoxy phenyl)-3- (substituted phenyl)-prop-2-en-1-one
(3a-h) and structurally characterized by using FT-IR,
1
H NMR,
13
C NMR, Mass
and Elemental analysis. The synthesized molecules were biologically eval-
uated for their in vitro anticancer activity against human breast adenocar-
cinoma (MCF-7), liver cancer (Hep-G2) and leukaemia cancer (K-562) cell
line using Sulforhodamine B (SRB) bioassay technique. From the all syn-
thesized compounds 5a, 5c, 5d, and 5e exhibited potent anticancer activity
(GI
50
= <10μg/ml) as compared to the controlled drug 5-Fluorouracil (5-FU)
(GI
50
=44.5μg/ml) and Adriamycin (ADR) (GI
50
= <10μg/ml) on MCF-7 cell
lines. Besides this, all the synthesized compounds have exhibited moderate
activity against human liver cancer (Hep-G2) and leukaemia cancer (K-562)
cell lines. In addition, molecular docking studies were also explored in order to
study the probable binding speciϐicity into the active site of Epidermal Growth
Factor Receptor tyrosine kinase (EGFR) (PDB ID: 1M17) using Molegro Virtual
Docker Evaluation 2013 6.0.1 (MVD). Based on the molecular docking result,
it was found that compound 5a exhibited the best interaction with the above
target (i.e., EGFR) by interacting with speciϐic amino acid residues such as: Thr
766, Gin 767, Thr 830, Cys 575, Ala 719 and Met 769.
*
Corresponding Author
Name: Tapan Kumar Maity
Phone: +919432299486
Email: jutkmaity@yahoo.com
ISSN: 0975-7538
DOI: https://doi.org/10.26452/ijrps.v12i2.4759
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INTRODUCTION
Globally, cancer is one of the serious and dreadful
diseases characterized by the uncontrolled, rapid,
and pathological proliferation of cells (Chavan et al.,
2018). In underdeveloped countries incidence and
mortality rate due to cancer increases day to day
because of the growth and aging of the popula-
tion (Suma et al., 2019). As per a survey by GLOBO-
CAN in 2018, over 18.1 million new cancer cases and
9.6 million deaths till now and the cases may grad-
ually raise up to 23.6 million by 2030 (Suma et al.,
2019; Santosh et al., 2019; Jemal et al., 2011).
Despite surgery, radiation and chemotherapy, can-
cer is still the second leading cause of death after
1648 © International Journal of Research in Pharmaceutical Sciences