T 2 and T 1 MRI in Articular Cartilage Systems Nina M. Menezes, 1 Martha L. Gray, 1,2 James R. Hartke, 3 and Deborah Burstein 1,4 * T 2 and T 1 have potential to nondestructively detect cartilage de- generation. However, reports in the literature regarding their di- agnostic interpretation are conflicting. In this study, T 2 and T 1 were measured at 8.5 T in several systems: 1) Molecular suspen- sions of collagen and GAG (pure concentration effects): T 2 and T 1 demonstrated an exponential decrease with increasing [collagen] and [GAG], with [collagen] dominating. T 2 varied from 90 to 35 ms and T 1 from 125 to 55 ms in the range of 15–20% [collagen], indicating that hydration may be a more important contributor to these parameters than previously appreciated. 2) Macromole- cules in an unoriented matrix (young bovine cartilage): In collagen matrices (trypsinized cartilage) T 2 and T 1 values were consistent with the expected [collagen], suggesting that the matrix per se does not dominate relaxation effects. Collagen/GAG matrices (na- tive cartilage) had 13% lower T 2 and 17% lower T 1 than collagen matrices, consistent with their higher macromolecular concentra- tion. Complex matrix degradation (interleukin-1 treatment) showed lower T 2 and unchanged T 1 relative to native tissue, consistent with competing effects of concentration and molecu- lar-level changes. In addition, the heterogeneous GAG profile in these samples was not reflected in T 2 or T 1 . 3) Macromolecules in an oriented matrix (mature human tissue): An oriented collagen matrix (GAG-depleted human cartilage) showed T 2 and T 1 varia- tion with depth consistent with 16 –21% [collagen] and/or fibril orientation (magic angle effects) seen on polarized light micros- copy, suggesting that both hydration and structure comprise im- portant factors. In other human cartilage regions, T 2 and T 1 ab- normalities were observed unrelated to GAG or collagen orienta- tion differences, demonstrating that hydration and/or molecular- level changes are important. Overall, these studies illustrate that T 2 and T 1 are sensitive to biologically meaningful changes in cartilage. However, contrary to some previous reports, they are not specific to any one inherent tissue parameter. Magn Reson Med 51:503–509, 2004. © 2004 Wiley-Liss, Inc. Key words: cartilage; MRI; Gd-DTPA 2- ; T 2 ; T 1 Osteoarthritis (OA) is the most common form of arthritis, currently affecting over 20 million people in the U.S. alone. Among the earliest events in OA are molecular-level changes in the two largest constituents of the cartilage extracellular matrix, glycosaminoglycans (GAG) and col- lagen (1). Specifically, GAG loss and collagen breakdown herald the onset of OA (1,2). Thus, the early diagnosis of OA requires the ability to noninvasively and nondestruc- tively detect degenerative changes in GAG concentration and collagen network integrity, a goal that has become increasingly important as early-intervention therapies are developed. To this end, MRI has proven promising. Several MRI parameters are actively being investigated for their ability to reflect biochemical and structural information relevant to the early stages of OA. However, the interpretation of these parameters has not been fully elucidated. The main goal of this work was to focus on two parameters in par- ticular—T 2 and T 1 —and further investigate these MR pa- rameters in model systems of cartilage. T 2 has been studied extensively in cartilage. T 2 has several sources of contributions. However, the current lit- erature largely focuses on the source of T 2 contrast in cartilage due to magic angle effects caused by the highly organized collagen network of cartilage (3– 8). However, Mosher et al. (9) have recently suggested that the magni- tude of the magic angle effect in cartilage is small in in vivo situations, and T 2 has also been investigated for its dependence on hydration (collagen concentration) (10 – 13) and GAG concentration (14). The literature regarding T 1 in cartilage provides con- flicting results. One study found T 1 to be sensitive to protein weight, concentration, and structure in suspen- sions (15), suggesting that it may be sensitive to collagen in cartilage. Studies of human cartilage from joint replace- ment surgery found no correlation between T 1 and GAG (14). Instead, T 1 was found to provide similar information to T 2 . On the other hand, other studies demonstrated that T 1 was shown to have high sensitivity to GAG in suspen- sions (16,17) and GAG loss in bovine cartilage induced by trypsin (16 –21), an enzyme that causes GAG loss but spares intact collagen. Additionally, T 1 has been found to be unchanged following treatment with collagenase (an enzyme that cleaves collagen); together, these results lead the authors to suggest that T 1 is selectively sensitive to GAG (17,18). In light of these conflicting results, the aim of this study was to measure T 2 and T 1 in systems from the simplest to most complex: suspensions of cartilage constituents (mo- lecular suspensions without a matrix), bovine calf models (structured macromolecular matrices that have no overall orientation), to human tissue (oriented macromolecular matrices). For the bovine and human samples we first investigate collagen matrices (GAG-depleted tissue) and then GAG/collagen matrices (normal tissue), and finally complex degradation and disease models. dGEMRIC (de- layed gadolinium-enhanced MRI of cartilage) and Tolu- idine blue histology were used to assess GAG and polar- ized light microscopy was used to assess collagen orienta- tion for comparison to the T 2 and T 1 results. 1 Harvard–Massachusetts Institute of Technology Division of Health Sciences & Technology, Cambridge, Massachusetts. 2 Department of Electrical Engineering & Computer Science, Massachusetts Institute of Technology, Cambridge, Massachusetts, and New England Bap- tist Bone and Joint Institute, Boston, Massachusetts. 3 Pharmacia Corp., St. Louis, Missouri. 4 Department of Radiology, Beth Israel Deaconess Medical Center, Boston, Massachusetts. Grant sponsor: National Institutes of Health; Grant numbers: AR42773; RR14792; Grant sponsors: Edward Hood Taplin Professorship (to M.L.G.) and the Natural Sciences and Engineering Research Council of Canada (to N.M.M.). *Correspondence to: Deborah Burstein, Ph.D., Beth Israel Deaconess Medi- cal Center, Harvard Institutes of Medicine, room 148, 4 Blackfan Circle, Boston, MA 02115. E-mail: dburstei@bidmc.harvard.edu Received 19 February 2003; revised 8 October 2003; accepted 8 October 2003. DOI 10.1002/mrm.10710 Published online in Wiley InterScience (www.interscience.wiley.com). Magnetic Resonance in Medicine 51:503–509 (2004) © 2004 Wiley-Liss, Inc. 503