Research Article
Isolation and Characterization of Cellulose Nanofibers from
Gigantochloa scortechinii as a Reinforcement Material
Chaturbhuj K. Saurabh,
1
Asniza Mustapha,
1
M. Mohd. Masri,
1
A. F. Owolabi,
2
M. I. Syakir,
1
Rudi Dungani,
3
M. T. Paridah,
4
M. Jawaid,
4
and H. P. S. Abdul Khalil
1
1
School of Industrial Technology, Universiti Sains Malaysia, 11800 Penang, Malaysia
2
Federal Institute of Industrial Research Oshodi, Lagos 25016, Nigeria
3
School of Life Sciences and Technology, Gandung Labtex XI, Institut Teknologi Bandung, Bandung 40132, Indonesia
4
Institute of Tropical Forestry & Forest Products, Universiti Putra Malaysia, 43400 Serdang, Malaysia
Correspondence should be addressed to H. P. S. Abdul Khalil; akhalilhps@gmail.com
Received 28 April 2016; Revised 3 June 2016; Accepted 16 June 2016
Academic Editor: Zeeshan Khatri
Copyright © 2016 Chaturbhuj K. Saurabh et al. Tis is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly
cited.
Cellulose nanofbers (CNF) were isolated from Gigantochloa scortechinii bamboo fbers using sulphuric acid hydrolysis. Tis
method was compared with pulping and bleaching process for bamboo fber. Scanning electron microscopy, transmission electron
microscopy, Fourier transform infrared spectroscopy, X-ray difraction, and thermogravimetric analysis were used to determine the
properties of CNF. Structural analysis by FT-IR showed that lignin and hemicelluloses were efectively removed from pulp, bleached
fbers, and CNF. It was found that CNF exhibited uniform and smooth morphological structures, with fber diameter ranges from 5
to 10 nm. Te percentage of crystallinity was signifcantly increased from raw fbers to cellulose nanofbers, microfbrillated, along
with signifcant improvement in thermal stability. Further, obtained CNF were used as reinforcement material in epoxy based
nanocomposites where tensile strength, fexural strength, and modulus of nanocomposites improved with the addition of CNF
loading concentration ranges from 0 to 0.7%.
1. Introduction
Over the years, numerous studies have been performed to
fnd the ideal cellulosic reinforcing material from natural
plant fbers. Bamboo is possibly an ideal source for cellulose
based nanofbers. It is a fast growing plant and widely
considered as an excellent source of cellulose fbers that pos-
sess relatively small microfbrillar angles and high cellulose
content [1]. Malaysia is endowed with more than 50 bamboo
species. Among these, almost 14 species are commercially
exploited [2]. Gigantochloa genus is one of the most utilized
bamboos in Malaysia due to its uniformity in size, thick culms
wall, and ease of cultivation, which makes this bamboo genus
a good choice for industrial usage [3].
Studies on cellulosic plant fbers for various applications
are widely done since they are sustainable, green, and envi-
ronmental friendly. Easy processing, low cost, low energy
consumption, light weight, excellent specifc strength, low
environmental hazard, and renewability and recyclability of
the reinforced green composite have generated great interest
among researchers over conventional synthetic reinforced
fbers [4, 5]. Te utilization of bamboo fbers in composites
has attracted interest because of its biodegradability and clean
emissions [6, 7]. Te incorporation of bamboo fber improves
certain properties of the polymer composite matrix (i.e.,
fracture toughness and impact behavior); however, fexural
strength of composites was not signifcantly afected [8–
10]. It is believed that the poor compatibility between the
cellulose and polymer matrix causes the low fexural strength
in cellulose reinforced composite materials. Te poor matrix
accessibility increases the interfacial tension between cel-
lulose fbers and polymeric matrices, thus increasing the
porosity of composites [11, 12]. Tus there is need to develop
a novel methodology for the production of cellulose fbers
which have better compatibility with the polymeric matrices.
Hindawi Publishing Corporation
Journal of Nanomaterials
Volume 2016, Article ID 4024527, 8 pages
http://dx.doi.org/10.1155/2016/4024527