J. Eng. Technol. Sci., Vol. 53, No. 3, 2021, 210309
Received June 11
th
, 2020, Revised December 28
th
, 2020, Accepted for publication April 1
st
, 2021.
Copyright ©2021 Published by ITB Institute for Research and Community Services, ISSN: 2337-5779,
DOI: 10.5614/j.eng.technol.sci.2021.53.3.9
Optimization and Modeling of Ammonia Removal from Aqueous
Solutions by Using Adsorption on Single-walled Carbon
Nanotubes
Arsalan Jamshidi
1
, Soheila Rezaei
2
, Ghasem Hassani
2, *
, Roohullah Jahanpour
1
&
Hossein Marioryad
1
1
Department of Environmental Health Engineering, Yasuj University of Medical
Sciences, Shahid Dastjerdi St, Imam Hossein Sq., Yasuj 7591875114, Iran
2
Social Determinants of Health Research Center, Yasuj University of Medical Sciences,
Shahid Dastjerdi St, Imam Hossein Sq., Yasuj 7591875114, Iran
*E-mail: ghhassani64@gmail.com
Highlights:
The highest adsorption was obtained in alkaline conditions (pH = 9.5) with a yield of
90%.
The Freundlich isotherm had the highest conformity with the data and is considered
the best model for describing adsorbent properties.
First-order kinetics had more conformity with the data compared with second-order
kinetics.
Abstract. Due to the health effects of ammonia as an environmental pollutant,
such as its odor, corrosion, algae phenomenon, etc., a method should be adopted
to remove it from wastewater. In this study, removal of ammonia from
hypothetical wastewater was investigated using adsorption on SWCNTs. The
Design-Expert software was used to design the experiments and optimize the
parameters that are effective in the adsorption performance of carbon nanotubes
(CNTs), such as contact time, adsorbent dosage, pH, temperature, and ammonia
concentration. The results revealed that the maximum adsorption with a
performance of 90% was attained at a pH of 9.5. In addition, the adsorption
performance was enhanced by increasing adsorption time and adsorbent dosage.
Furthermore, increasing the temperature and the adsorbate quantity led to a
decrease in the adsorption performance.
Keywords: ammonia removal; carbon nanotubes; isotherm; kinetics; response surface
methodology.
1 Introduction
Urban development, the emergence of a variety of industries, the increased level
of social welfare and other factors have caused irreparable damage to the
environment. One of the major environmental sources that have been