Journal of Crystal Growth 262 (2004) 78–83 In situ study of GaAs growth mechanisms using tri-methyl gallium and tri-ethyl gallium precursors in metal-organic vapour phase epitaxy M. Pristovsek* ,1 , M. Zorn, M. Weyers Ferdinand-Braun-Institut f . ur H . ochstfrequenztechnik, Albert-Einstein-StraX e 11, D-12489 Berlin, Germany Received 12 June 2003; accepted 14 October 2003 Communicated by D.W. Shaw Abstract A comparative study of GaAs (0 0 1) growth from tri-methyl gallium (TMGa) and tri-ethyl gallium (TEGa) was performed in metal-organic vapour phase epitaxy. The growth surfaces were characterised by reflectance anisotropy spectroscopy (RAS). Three distinct shapes of the RAS spectra typical for certain growth parameter regions were observed for both precursors. The RAS spectra typical for the growth at low temperatures correspond to kinetic limited growth and the surface is covered by adsorbates. At slightly higher temperatures in mass transport limited growth mode, a more gallium-rich surface appears with both precursors. In the case of TEGa, the lack of arsenic on the surface below 500  C is simply due to the lack of decomposed AsH 3 : However, using TMGa gallium-rich surfaces are already found below 600  C. We propose steric hindrance of As diffusion by methyl groups around the incorporation sites and forced arsenic desorption by the formation of methyl arsine as the cause. At typical buffer growth temperatures above 600  C, the surfaces during growth are identical to the AsH 3 stabilised arsenic-rich pre-growth surfaces for both gallium precursors. r 2003 Elsevier B.V. All rights reserved. PACS: 68.35.Bs; 68.35.Fx; 68.43.Mn; 68.47.Fg; 68.55.Ac; 78.68.+m; 81.15.Kk; 82.33.Ya Keywords: A1. Reflection anisotropy spectroscopy; A1. Growth models; A3. Metalorganic vapor phase epitaxy; B2. Semiconducting gallium arsenide 1. Introduction The growth of gallium arsenide in metal-organic vapour phase epitaxy (MOVPE) has been investi- gated for more than 30 years. Even in the first publication on crystal growth in MOVPE tri- methyl gallium (TMGa) and tri-ethyl gallium (TEGa) were used [1], and both have been used ever since. The choice of the precursor is mostly ARTICLE IN PRESS *Corresponding author. Tel.: +49-30-6392-2672; fax: +49- 30-6392-2685. E-mail address: prissi@physik.tu-berlin.de (M. Pristovsek). 1 Present address: TU-Berlin, PN6-1, Hardenstr. 36, D-10623 Berlin, Germany. Tel.: +49-30-314-22076; fax: +49-30-314- 21769. 0022-0248/$ - see front matter r 2003 Elsevier B.V. All rights reserved. doi:10.1016/j.jcrysgro.2003.10.044