1 Supporting Information Enantioselective Copper-Catalyzed Borylative Cyclization with Cyclic Imides Andrew Whyte, Alexa Torelli, Bijan Mirabi, and Mark Lautens* <mark.lautens@utoronto.ca> Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, M5S 3H6, Canada Table of Contents General Considerations .............................................................................................................................. 2 Synthesis of Substrates – General Procedure 1 ........................................................................................ 3 Characterization of Substrates .................................................................................................................. 4 Catalytic Reaction Procedure .................................................................................................................. 21 Product Characterization......................................................................................................................... 22 Large Scale Experiment ........................................................................................................................... 51 Derivatizations........................................................................................................................................... 52 Failed Substrates ....................................................................................................................................... 57 X-Ray Data for Product 2e....................................................................................................................... 59 NMR Spectra ............................................................................................................................................. 77