Research Article
DevelopmentofUVSpectrophotometricProceduresfor
DeterminationofAmlodipineandCelecoxibinFormulation:
UseofScalingFactortoImprovetheSensitivity
MaheshAttimarad ,
1
KatharigattaNarayanaswamyVenugopala ,
1,2
BandarE.Aldhubiab ,
1
AnroopBalachandranNair,
1
NagarajaSreeHarsha ,
1
ShinuPottathil,
3
andSabahH.Akrawi
1
1
Department of Pharmaceutical Sciences, College of Clinical Pharmacy, King Faisal University, Al-Hofuf,
Al-Ahsa 31982, Saudi Arabia
2
Department of Biotechnology and Food Technology, Durban University of Technology, Durban 4001, South Africa
3
Department of Biomedical Sciences, College of Clinical Pharmacy, King Faisal University, Al-Hofuf,
Al-Ahsa 31982, Saudi Arabia
Correspondence should be addressed to Mahesh Attimarad; mattimarad@kfu.edu.sa
Received 30 June 2019; Revised 18 September 2019; Accepted 1 October 2019; Published 7 December 2019
Academic Editor: Sarfaraz Ahmed Mahesar
Copyright © 2019 Mahesh Attimarad et al. is is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is
properly cited.
FDA has recently approved a new fixed-dose combination of amlodipine besylate (AMD) and celecoxib (COX) for the treatment
of hypertension and osteoarthritis. No analytical method has been reported for analysis of these two analytes so far. Hence, to
monitor the quality and quantity in the formulation of AMD and COX a simple, accurate, precise, economical, and eco-friendly
spectroscopic analytical method has been established. e first method involves the determination of AMD and COX by the first
derivative UV spectroscopic method with scaling factor 10. However, the second method was based on the direct measurement of
UV absorbance of AMD at 364.3 nm and ratio first derivative UV spectroscopic method for COX. Both methods showed good
linearity in the range of 5 to 40 μg/ml for COX, whereas AMD showed linearity in the range of 0.5 to 10 μg/ml in first derivative
method with scaling factor 10 and 1 to 10 μg/ml in the second method with good correlation coefficient (R
2
> 0.998). Both the
methods were validated for LOD, LOQ, accuracy, precision, recovery studies, and stability as per the ICH guidelines, and the
validated results were well within the acceptable range. Both the methods were successfully utilized for the determination of AMD
and COX in the presence of each other in the formulation, and statistically compared between the proposed methods. erefore,
the proposed procedures can be utilized for regular quality control studies.
1.Introduction
Hypertension and osteoarthritis (OA) are major health
problems in the middle- and old-age population. Generally,
these two diseases coexist, and 40% of OA patients were
diagnosed for hypertension [1]. However, the treatment for
these two diseases is challenging, because of the adverse
effects of NSAIDs on the blood pressure [2]. Nevertheless,
celecoxib (COX, Figure 1(a)) was found to be a better choice
because it has low risk on blood pressure than ibuprofen,
naproxen, or other NSAIDs, and COX has low gastroin-
testinal and kidney toxicity [3, 4]. Hence, FDA has recently
approved a fixed-dose combination of calcium channel
blocker, amlodipine besylate, and selective COX-2 inhibitor,
celecoxib, for the treatment of hypertension and OA [5].
Amlodipine besylate (AMD, Figure 1(b)), a long-acting
calcium channel blocker, is a dihydropyridine derivative
extensively used for the management of hypertension and
angina pectoris [6]. Several analytical methods were de-
scribed in the literature for quantification of AMD alone and
Hindawi
Journal of Spectroscopy
Volume 2019, Article ID 8202160, 10 pages
https://doi.org/10.1155/2019/8202160