Materials Science & Engineering A 799 (2021) 140012
Available online 11 August 2020
0921-5093/© 2020 Elsevier B.V. All rights reserved.
Thermal stability, microstructure and texture evolution of
thermomechanical processed AlCoCrFeNi
2.1
eutectic high entropy alloy
M.H. Asoushe
a
, A. Zarei Hanzaki
a, *
, H.R. Abedi
b, *
, B. Mirshekari
a
, T. Wegener
c
, S.
V. Sajadifar
c
, T. Niendorf
c
a
Hot Deformation and Thermomechanical Processing Laboratory of High-Performance Engineering Materials, School of Metallurgy and Materials Engineering, College of
Engineering, University of Tehran, Tehran, Iran
b
School of Metallurgy & Materials Engineering, Iran University of Science and Technology (IUST), Tehran, Iran
c
Universit¨ at Kassel, Institut für Werkstofftechnik (Materials Engineering), 34125, Kassel, Germany
A R T I C L E INFO
Keywords:
Eutectic high entropy alloy
Cast structure
Thermal stability
Thermomechanical processing
Texture evolution
ABSTRACT
The microstructural and texture evolutions of as-cast AlCoCrFeNi
2.1
eutectic high entropy alloy (EHEA) have
been investigated in the course of thermomechanical processing at the temperature range of 25–500
◦
C. Inter-
estingly, compared with other conventional casting structures, signifcant strength-ductility ratio has been
achieved at room temperature. In addition, the volume fractions of the constituent phases: soft FCC (face-
centered cubic), and the hard BCC (body-centered cubic) phases, do not signifcantly change from room to
elevated deformation temperatures. In fact, the strength and ductility have not been decreased at higher tem-
peratures which represent the mechanical stability of the alloy in the examined temperature range. From room
temperature up to 300
◦
C, the dendrites have been stretched and broken with a slight deviation from the load
direction, whereas at higher temperature of 500
◦
C the dendrites have been rotated relative to the direction of
load before fracture. Texture examination reveals the formation of a random texture in the initial and deformed
states due to simultaneous contribution of different infuencing factors such as stretching of dendrites during
deformation, the dendrite morphology changes, and the presence of hard and soft phases and their interaction
with each other.
1. Introduction
Owing to the limited resources, the development of new materials
has drawn much attention as the mainly upfront challenge of the next
generation. Conventional alloys are based on one or two main elements
with relatively small amount of alloying elements for modifcation of the
evolved microstructure [1]. However, the high entropy alloys (HEAs)
are a new class of materials which are commonly defned as alloys
containing four or more elements with equimolar or near-equimolar
compositions; with atomic fraction between 5 and 35 at.% for each
element forming a single or dual phase structure despite multiple ele-
ments [2,3]. There are mainly four core effects that distinguish this
category of alloys from the conventional ones: (i) high-entropy effect (ii)
sluggish diffusion (iii) severe lattice distortion and (iv) cocktail effect
[3]. Previous researches have shown promising properties of HEAs such
as signifcant mechanical properties, noticeable corrosion and wear
resistance, thermal stability at elevated temperatures [4,5], and sluggish
diffusion kinetics [6]. These specifed properties categorize HEAs as a
suitable candidate for high temperature applications.
The balance between the strength and ductility is considered as a
main challenge to schedule the processing routes of HEAs [7]. In this
regard, single phase solid solution FCC structured HEAs show merely
good ductility [8,9] while single-phase solid solution BCC structured
HEAs possess high strength [10]. Therefore a proper combination of the
constituent phases (BCC and FCC phase fractions) can signifcantly
enhance mechanical properties [11]. However, simply introducing a
combination of FCC and BCC phases, without a proper structural design,
could not solve the problem [12]. Besides, the problems resulting from
casting e.g. segregation and shrinkage cavities may cause deterioration
and heterogeneity in mechanical properties [13,14]. To overcome this
problem, the eutectic HEAs alloys have been developed which beneft
from acceptable cast-ability [3]. Since the eutectic reaction is an
isothermal transformation, there is no solidifcation temperature range
and both the segregation and shrinkage cavity can be alleviated [7]. The
* Corresponding authors.
E-mail addresses: zareih@ut.ac.ir (A.Z. Hanzaki), habedi@iust.ac.ir (H.R. Abedi).
Contents lists available at ScienceDirect
Materials Science & Engineering A
journal homepage: http://www.elsevier.com/locate/msea
https://doi.org/10.1016/j.msea.2020.140012
Received 19 May 2020; Received in revised form 27 July 2020; Accepted 28 July 2020