International Journal of Engineering and Advanced Technology (IJEAT)
ISSN: 2249 – 8958, Volume-8 Issue-3, February 2019
294
Published By:
Blue Eyes Intelligence Engineering
& Sciences Publication
Retrieval Number: C5884028319 /19©BEIESP
Strength of Cement Mortar Using Nano Oxides:
An Experimental Study
Mohan Kantharia, Pankaj Mishra, M.K. Trivedi
Abstract: Cement mortar is one of the important materials
which plays key role in maximising the durability of a building.
Strength, permeability, thermal insulation, freeze and thaw
resistance, Chloride-ion penetration, carbonation, hydration,
weathering are the factors affecting the overall performance of
the cement mortar. So many new ingredients are being used as
admixture have been investigated for making the mortar of high
performance. Various nano materials are constituting the
advance engineering products with smart working. Some
industrial waste like blast furnace slag, fly ash, silica fume, also
incorporated in cement concrete for making mortar economical.
In this Experimental study nano oxide of Zinc, aluminium, and
silicon have been investigated in cement mortar and compared. It
is found that all nano materials are not having the similar effect.
Key Words: - Nano Zinc oxide, compressive strength, cement
mortar.
I. INTRODUCTION
In modern construction work cement is an essential
component. In modern concrete technology nano particles
are widely employed for getting noble properties. During
Last 20-25 years the use of nano materials is increased
tremendously, because of high specific surface area the
reactivity of nano particles is very high. In other fields such
as medicine, glass industry, paints nano technology has been
already proved beneficial, nowadays, scientists’ interest
rapidly growing in use of nano particles in cementing
materials for durability and engineering properties. During
20
th
century the strength of concrete up to 50 MPa was
considered as High-performance concrete, but with
advancement of construction technology now concrete 150
MPa is known as high performance concrete, now even
Ultra high-performance concrete can be produced. Extensive
research Has been done for making concrete more advance
by many admixtures, pozzolans, polymers etc. Some
researchers have shown that by adding nano particles the
cement concrete become stronger and sensitive to
temperature and strain. However, cost will also increase
slightly. Generally, superplasticizers are used with nano
materials because they reduce workability. Nano particles
are very fine hence fill the micro-pores of the materials
hence affect the properties of the material, due to pore
filling, compressive strength and permeability affected.
Nano material increases the crystallization in hydrates,
water permeability decreases.
Revised Manuscript Received on 24 February 2019.
Mohan Kantharia, Assistant Professor, Department of Civil
Engineering, Amity School of Engineering and Technology Amity
University Madhya Pradesh. India.
Dr. Pankaj Mishra, Assistant Professor, Department of Physics,
Amity School of Engineering and Technology Amity University Madhya
Pradesh. India.
Dr. Manoj Kumar, Trivedi, Professor, Department of Civil
Engineering, Madhav Institute of Technology and Science Gwalior India.
Nano particles not only fills the voids, improves hydration
reaction, also by pozzolanic reactions with calcium
hydroxide make more CSH gel which improves the
mechanical strength and durability. To understand the effect
on hydration of cement many nano materials have been
experimented by using ZnO
2
, Cr
2
O
3
, TiO
2
, Al
2
O
3
, SiO
2
Multiwalled carbon nanotube etc.
II. LITERATURE SURVEY
A. Addition of nano alumina in cement mortar
Many researchers have shown the improvement in
mechanical properties by adding nano alumina.
Compressive strength split tensile strength, workability,
setting time etc varied while nano admixtures are used.
Many properties of cement concrete may be corelated to
compressive and tensile strength, hence measurement of
these properties is mandatory.
M. R. Arefi et al (2011). In this work alumina is added to
cement and found that up to 3 % improvement in strength is
seen, then decreases. images for SEM also shows that
calcium hydroxide reduces at 3% nano alumina. but at 5%
alumina strength decreases, this may be due to nano particle
are more than the required to combined with lime which
liberated during hydration process. thus, excess silica
leaches cause deficiency in strength. high surface area of
nano to be added in correct quantity otherwise their
agglomeration appears. Because of high surface area nano
particles consume liberated Ca(OH)
2
and fill the voids of C-
S-H gel denser microstructure produces more compressive
strength.
Ali Nazari et al (2010). They have investigated that nano
alumina in cement mortar improves the split tensile strength
and flexural strength and setting time has decreased. Best
results are found at 1 % of alumina while more than 2%
strength decreases than control mix. Curing time was 7, 28,
90 days. higher percentage of admixture excess silica
leaches cause strength deficiency. Increase in strength may
be due to rapid consumption of calcium hydroxide which
formed during hydration. Setting times decreases because of
higher specific surface area has faster hydration reaction. In
this paper nano alumina of average diameter 15 nm was
used workability and compressive strength were found. Four
samples of admixtures 0.5 %, 1.0%, 1.5 % and 2 % and
concluded that at 1 % alumina best results in strength.
Workability decreases at higher % of nano alumina giving
low slump value. therefore, use of super plasticizer is
necessary.
B. Addition of nano Zinc Oxide in cement mortar
Using ZnO, and Al-ZnO, enhances mechanical properties.