Merazga et al.
54
Effect of Thermal Annealing on the Optical and
Structural Properties of the a-SiC Thin Films Deposited
by DC Magnetron Sputtering
NanoWorld Journal
Research Article Open Access
https://doi.org/10.17756/nwj.2017-047
Saloua Merazga
1*
, A. Kefous
1
, A. Brighet
2
and M. Kechouane
2
1
CRTSE, Division Couches Minces Surfaces et Interfaces, 02 Bd Frantz Fanon, BP 140 Alger 7-merveilles, Alger, Algeria
2
Université des Sciences et de la Technologie Houari Boumediene, Faculté de Physique, BP 32 El Alia, 16111, Alger, Algeria
*
Correspondence to:
Saloua Merazga, PhD
CRTSE, Division Couches Minces Surfaces et
Interfaces, 02 Bd Frantz Fanon, BP 140 Alger
7-merveilles, Alger, Algeria
E-mail: merazgas@yahoo.fr
Received: January 19, 2017
Accepted: September 18, 2017
Published: September 21, 2017
Citation: Merazga S, Kefous A, Brighet A,
Kechouane M. 2017. Efect of Termal Annealing
on the Optical and Structural Properties of the
a-SiC Tin Films Deposited by DC Magnetron
Sputtering. NanoWorld J 3(3): 54-58.
Copyright: © 2017 Merazga et al. Tis is an Open
Access article distributed under the terms of the
Creative Commons Attribution 4.0 International
License (CC-BY) (http://creativecommons.
org/licenses/by/4.0/) which permits commercial
use, including reproduction, adaptation, and
distribution of the article provided the original
author and source are credited.
Published by United Scientifc Group
Abstract
Hydrogenated Amorphous silicon carbide (a-SiC:H) thin flms were
prepared by DC magnetron sputtering technique using 6H-SiC polycrystalline
target in a mixture of H
2
and Ar gas. Tey were thermally annealed at various
temperatures up to 800 °C. Te a-SiC:H flms were deposited at diferent
hydrogen partial pressure rates varying from 0 to 9 sccm on p-type Si(100)
and Corning glass 9075 substrates. Te annealing temperatures were varied
and the samples were characterized by Infrared spectroscopy (FTIR), Raman
spectroscopy and Ellipsometry spectroscopy. Te previous results of infrared and
Raman spectroscopy reveal structural modifcations in the material structure of
the layers through a reduction of the thickness and optical gap and the variation
of the refractive index during the annealing.
Keywords
Amorphous SiC, Annealing, Sputtering, DC magnetron, Gap
Introduction
Annealing of hydrogenated silicon carbide (a-SiC:H) thin flms has attracted
great interest in optoelectronics and photovoltaic domain [1] for the flms prepared
by plasma enhanced chemical vapor deposition(PECVD), due to their chemical
stability and interesting optical and electronic properties. Tis type of material
has a major advantage, which consists of its possibility to modify its properties by
either varying the preparation conditions or the flm composition [2, 3].
Te annealing efect on a-Si
x
C
1−x
:H thin flms have been reported by several
authors [2-5]. A.L. Baia Neto et al. reported the decrease of Si-H bonds at low
annealing temperatures, whereas the C-H bonds are only afected at temperatures
higher than 500 °C. On near stoichiometric a-SiC:H flms deposited using a RF
glow discharge system. M. Kuenle et al. investigated that the deposited flms
became amorphous directly after deposition and nanocrystalline after annealing
at 1300 °C. Tereabout, D. H. Yoon founded that an annealing process results
in structural rearrangement and evacuation of hydrogen atoms from CH
n
and
SiH
n
bonds. However, F. Demichelis and G. Kaniadakis reported that the optical
parameters of a-SiC:H flms deposited by sputtering system strongly depend on
the preparation conditions and appear to be sensitive functions of the network
disorder [6].
However, the infuence of preparation conditions on the thermal stability of
amorphous SiC:H flms remain unclear up to now.
All these investigations are carried out in order to show the great importance
of the thermal treatment study of the a-SiC:H. Many phenomena can occur