CHEMICAL ENGINEERING TRANSACTIONS
VOL. 27, 2012
A publication of
The Italian Association
of Chemical Engineering
Online at: www.aidic.it/cet
Guest Editors: Enrico Bardone, Alberto Brucato, Tajalli Keshavarz
Copyright © 2012, AIDIC Servizi S.r.l.,
ISBN 978-88-95608-18-1; ISSN 1974-9791
Biodegradation of Aromatic Compounds by a Halophilic
Archaeon Isolated from the Dead Sea.
Sara Cuadros-Orellana
a
, Metchild Pohlschröder
b
, Matthew J. Grossman
c
and
Lucia R. Durrant
c*
a
Centro de Pesquisas René Rachou (CPqRR/Fiocruz), Belo Horizonte-MG, Brazil
b
Department of Biology, School of Arts and Sciences, University of Pennsylvania, Philadelphia, PA, USA
c
Department of Food Science - FEA, University of Campinas (UNICAMP), Rua Monteiro Lobato, 80 CEP: 13083-
862 Campinas, São Paulo, Brazil
durrant@fea.unicamp.br
It is well established that aromatic compounds can be readily degraded in aerobic environments within
soils, sediments and waters with salinities up to and including that of seawater. However, little is known
about their metabolism in hypersaline environments. There is a growing interest in the development
and optimization of bioremediation processes to deal with environments with high salinity that are
contaminated with aromatic compounds. Among prokaryotes, haloarchaea are a group of
microorganisms living in hypersaline environments that may have a greater potential in degrading
pollutants than previously assumed and can be considered as a good environmental tool for
bioremediation. We enriched and isolated 10 halophilic archaea from Dead Sea water samples on the
basis of their ability to grow on p-hydroxybenzoic acid (pHBA) as the sole carbon and energy source.
All isolates showed identical total lipid profiles, but are metabolically very diverse. Strain L1, which is
also capable of growth on benzoic acid (BA), was chosen for biodegradation kinetics determination.
When grown in BA, strain L1 produced small amounts of a compound that co-chromatographed with
gentisic acid, which accumulated in the medium. The same did not occur when pHBA was the growth
substrate. A discussion on the possible metabolic pathways involved is included, and a preliminary
characterization of strain L1 is presented.
1. Introduction
Thalassic (sea water-derived) hypersaline environments are usually characterized by low water activity
and high temperatures. Biological activity dramatically decreases as sea water concentrates, as a
consequence of a
w
reduction, and so does biological diversity. The Dead Sea contains 340 g/L total
dissolved salts and is probably one of the most extreme examples of saline aquatic environments. Its
waters are devoid of life except for local more diluted sections originated from rare abundant rainfall in
the catchment area, mainly during winter, which may lead to discrete microbial blooms around the
edges (Bodaker, et al, 2010). Since the pioneer studies by Benjamin Elazari Volcani on the microbiota
of the Dead Sea in the early 1930s, a number of aerobic and anaerobic halophilic bacteria and archaea
have been isolated from Dead Sea water and sediments, or detected through molecular or
chemotaxonomic methods (Oren and Gurevich, 1995, Arahal et al. 1996, Rainey et al., 1995, Bodaker
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