S1 Anti-Markovnikov Rearrangement in Sulfur Mediated Allyllic C-H Amination of Olefins Zhong Zhang, Hongguang Du*, Jiaxi Xu* and Pingfan Li* State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology, Beijing 100029, China Email: dhg@mail.buct.edu.cn, jxxu@mail.buct.edu.cn, lipf@mail.buct.edu.cn Supporting Information Table of Contents I. General Information...................................................................................................................... S2 II. Compounds Chart.........................................................................................................................S3 III. Experimental Procedures and Characterization Data................................................................. S5 Preparation of alkene substrates............................................................................................... S5 Sulfur mediated allylic amination reactions............................................................................. S6 Characterization data of new compounds.................................................................................S7 IV. Copies of 1 H, 13 C and 19 F NMR Spectra................................................................................... S19 the 1 H and 13 C NMR spectra of 3aa............................................................................... S19 the 1 H and 13 C NMR spectra of 4aa............................................................................... S20 the 1 H and 13 C NMR spectra of 3ab............................................................................... S21 the 1 H and 13 C NMR spectra of 4ab............................................................................... S22 the 1 H and 13 C NMR spectra of 3ac............................................................................... S23 the 1 H and 13 C NMR spectra of 4ac............................................................................... S24 the 1 H and 13 C NMR spectra of 3ad............................................................................... S25 the 1 H and 13 C NMR spectra of 4ad............................................................................... S26 the 1 H and 13 C NMR spectra of mixture 5ad and 3ad................................................... S27 the 1 H and 13 C NMR spectra of 3ae............................................................................... S28 the 1 H and 13 C NMR spectra of 4ae............................................................................... S29 the 1 H and 13 C NMR spectra of 5ae............................................................................... S30 the 1 H and 13 C NMR spectra of 3af................................................................................ S31 the 1 H and 13 C NMR spectra of 4af................................................................................ S32 the 1 H and 13 C NMR spectra of 5af................................................................................ S33 the 1 H and 13 C NMR spectra of mixture 5ag and 3ag.................................................... S34 the 1 H and 13 C NMR spectra of 4ag............................................................................... S35 the 1 H and 13 C NMR spectra of 3ba............................................................................... S36 the 1 H and 13 C NMR spectra of 4ba............................................................................... S37 the 1 H, 13 C and 19 F NMR spectra of 3ca.........................................................................S38 the 1 H, 13 C and 19 F NMR spectra of 4ca.........................................................................S40 Electronic Supplementary Material (ESI) for ChemComm. This journal is © The Royal Society of Chemistry 2016