Original Article
ISSN (Online): 2456-8651
International Journal of Engineering Science Technologies
January-February 2022 6(1), 1–10
How to cite this article (APA): Hanan, A., Laghari, A. J., Solangi, M. Y., Aftab, U., Abro, M. I., Cao, D., Ahmed, M., Lakhan, M. N., Ali, A.,
Asif, A., and Shar, A. H. (2022). CDO/CO3O4 Nanocomposite as An Efficient Electrocatalyst for Oxygen Evolution Reaction in Alkaline
Media. International Journal of Engineering Science Technologies, 6(1), 1-10.doi: 10.29121/IJOEST.v6.i1.2022.259
1
CdO/Co
3
O
4
NANOCOMPOSITE AS AN EFFICIENT ELECTROCATALYST
FOR OXYGEN EVOLUTION REACTION IN ALKALINE MEDIA
Abdul Hanan
1
, Abdul Jaleel Laghari
2
, Muhammad Yameen Solangi
2
, Umair Aftab
2
,
Muhammad Ishaque Abro
2
, Dianxue Cao
1
, Mukhtiar Ahmed
3
, Muhammad Nazim Lakhan
4
, Amir
Ali
5
, Ali Asif
6
, Altaf Hussain Shar
4
1
Key Laboratory of Superlight Material and Surface Technology, College of Materials Science and Chemical
Engineering, Harbin Engineering University, PR China.
2
Department of Metallurgy and Materials Engineering, MUET, Jamshoro, Pakistan.
3
Institute of Process Engineering, University of Chinese Academy of Sciences, PR China.
4
School of Chemistry and Materials Science, University of Science and Technology of China, PR China.
5
College of Underwater Acoustic Engineering, Harbin Engineering University, PR China.
6
College of Nuclear Science and Technology, Fundamental Science on Nuclear Safety and Simulation
Technology Laboratory, Harbin Engineering University, PR, China.
Received 1 December 2021
Accepted 15 December 2021
Published 15 January 2022
Corresponding Author
Abdul Hanan, ahanansamo@gmail.com
DOI 10.29121/IJOEST.v6.i1.2022.259
Funding: This research received no
specific grant from any funding agency in
the public, commercial, or not-for-profit
sectors.
Copyright: © 2022 The Author(s). This is
an open access article distributed under
the terms of the Creative Commons
Attribution License, which permits
unrestricted use, distribution, and
reproduction in any medium, provided
the original author and source are
credited.
ABSTRACT
Electrochemical water splitting is one of the promising ways to enhance energy with
less outflow. In this regard different electrocatalysts have been reported for Oxygen
evolution reaction (OER) to get alternative of noble metal based electrocatalysts. In
this work, we have introduced Cadmium-oxide/Cobalt-oxide (CdO/Co3O4)
nanocomposite by co-precipitation chemical strategy with impressive OER
performance in alkaline medium. Almost 310 mV overpotential value is required to
achieve 10 mA/cm2 current density with Tafel slope value of 62 mV/Dec. The as
synthesized nanocomposite has stability of 6h as its longer electrochemical
performance.
Keywords: Electrochemistry, Oxygen Evolution Reaction, Electrocatalyst, Cobalt
Oxide, Cadmium Oxide
1. INTRODUCTION
Renewable energy has been playing a vital role since last decade as
emerging source of global energy. Electrochemical water splitting is one the
green way to get energy with less outflow for growing society Bhatti et al.
(2021), Kang and Kim (2021). Electrochemical OER is intensive, critical and
productive way for molecular oxygen from water oxidation Martini and Maia
(2021). OER requires four electron transfer reaction and high over-potential
required for reaction mechanism. That larger over-potential is the major
barrier for the researchers to get it at optimum level. Therefore, it is global
challenge to reduce the over-potential value to obtain efficient electrocatalyst
material for highly active OER performance Ahamad et al. (2020), Ahmed et
al. (2022).
Meanwhile, OER activity has been done by several non-precious metal
based electrocatalysts such as metal chalcogenide Majhi and Yadav (2021),