Glutathione S -Transferase Polymorphisms and the Synergy
of Alcohol and Tobacco in Oral, Pharyngeal,
and Laryngeal Carcinoma
Edward S. Peters,
1
Michael D. McClean,
2
Carmen J. Marsit,
3
Brian Luckett,
1
and Karl T. Kelsey
3
1
Division of Epidemiology, Louisiana State University Health Sciences School of Public Health, New Orleans, Louisiana; and
2
Department of Environmental Health, Boston University School of Public Health and
3
Department of Genetics
and Complex Diseases, Harvard School of Public Health, Boston, Massachusetts
Abstract
Investigations of the ability of polymorphisms in the
GSTM1, GSTT1 , and GSTP1 genes to alter susceptibility to
head and neck squamous cell carcinoma (HNSCC) have
examined gene-environment interaction in their detoxifica-
tion of tobacco-associated carcinogens. Little work has been
done to ask if these variant genes also modify the interaction
of tobacco and alcohol in the development of HNSCC. To
test this hypothesis, we conducted a case-control study,
enrolling 692 incident cases of HNSCC and 753 population
controls. Information about lifetime tobacco and alcohol use
was ascertained through questionnaires, and genotypes for
GSTM1, GSTT1 , and GSTP1 were determined from constitu-
tional DNA. Genotype frequencies were compared among
cases and controls, and the association between genotypes
and tobacco use was evaluated on cancer risk through
logistic regression. Deletion of GSTM1 was associated with
an increased risk for HNSCC [odds ratio (OR), 1.3; 95%
confidence interval (95% CI), 1.0-1.6]. GSTT1 deletion was
associated with a slight decreased HNSCC risk (OR, 0.8; 95%
CI, 0.6-1.0). Among those with GSTM1 present, the OR of
cancer for heavy smoking was 2.6 (95% CI, 1.6-4.3) compared
with 4.2 for those with the GSTM1 deleted (95% CI, 2.6-6.7).
The combination of consuming 10 to 20 alcohol drinks
weekly and smoking >45 pack-years was associated with a
13-fold elevated risk (OR, 12.6; 95% CI, 4.0-40.2) among the
GSTM1 deleted subjects compared with an OR of 3.6 (95%
CI, 1.5-8.7) among the GSTM1 present individuals. These
data (showing that the GSTM1 deletion affects on the tobacco
and alcohol synergy) suggest that the interaction of these
carcinogens is, at least in part, driven by alcohol, enhancing
thecarcinogenicactionoftobaccosmoke. (CancerEpidemiol
BiomarkersPrev2006;15(11):2196–202)
Introduction
Head and neck squamous cell carcinoma (HNSCC) is the 8th
most common cancer worldwide for both sexes, the 6th most
common cancer in developing nations, and is the 10th most
common cancer in the United States (1, 2). The use of tobacco
and alcohol accounts for f75% of all HNSCCs in the United
States (3, 4). Rothman (5) and Blot et al. (3) have shown that
alcohol and tobacco have both independent and synergistic
roles in the genesis of HNSCC, as strong dose-response
relationships for alcohol and for tobacco consumption as well
asamultiplicativeinteractionofbothareobservedinvirtually
all of the HNSCC studies published to date. Tobacco smoke is
well recognized as a complete carcinogen, but the mechanism
by which alcohol exerts its carcinogenicity remains unclear.
Alcohol may act as a solvent for other carcinogens or perhaps
generate and exacerbate coincident inflammation, producing
significant reactive oxygen species (6, 7). Although the
combined exposures of tobacco and alcohol are primarily
responsible for the genesis of this disease, interindividual
geneticvariabilitymayplayanimportantroleinmodifyingthe
potency of these carcinogens and mediating potential suscep-
tibility to the action of both tobacco and alcohol either
individually or as they interact to induce cancer (8, 9). Indeed,
genetic polymorphisms affecting the expression or activity of
metabolic enzymes responsible for the detoxification of
tobacco and alcohol are thought to influence an individual’s
susceptibility to oral cancer (10, 11).
Glutathione S -transferases (GST) are phase II xenobiotic
metabolizing enzymes directly involved in catalyzing the
conjugation of reactive intermediates of electrophilic xeno-
biotics with glutathione (8, 11, 12). The GSTs are composed of
four major groups: GSTA (a), GSTT1 (u), GSTM1 (A), and
GSTP1 (k). The u class of glutathione transferases is also well
known to activate haloalkanes (13), such as those found in the
chlorination by-products in treated drinking water (14, 15),
and methyl chloride, which is found in tobacco smoke (16).
GSTexpressionvariesamongindividuals,andthisvariationis
tissueandgenderspecific(17). GSTM1, GSTT1 ,and GSTP1 are
well known to be polymorphic, and deleted variants of the
GSTM1 and GSTT1 loci result in loss of functional activity
(18-20). Deletion of the GSTM1 and GSTT1 genes has been
reported in approximately 50% and 20% of the Caucasian
population, respectively (21-23). Two polymorphisms in the
GSTP1 gene, one at codon 105 with an A to G transition
resulting in an isoleucine to valine amino acid change and
anotheratcodon114(alaninetovalinesubstitution),havebeen
reported to cause differences in catalytic activity (9).
Various studies have shown positive associations between
the GSTM1 and GSTT1 null genotypes and increased risk for
skin, lung, bladder, and oral cancer (9, 24-29). Despite several
independentstudiesandsubsequentmeta-analysis,thereports
about the association of HNSCC and the GST variants remain
inconclusive (11, 30). The GSTs play an important role in the
metabolism of chemical carcinogens, especially with regard to
thosepresentintobaccosmoke.Further,althoughtobaccoand
alcohol are major independent risk factors for HNSCC, it is in
their interaction that the most profound risk of HNSCC is
incurred.Themechanismofthisinteractionisnotknown,and
2196
Cancer Epidemiol Biomarkers Prev 2006;15(11). November 2006
Received 6/20/06; revised 8/4/06; accepted 8/22/06.
Grant Support: NIH grants CA78609, CA100679 and The Flight Attendants Medical Research
Institute.
The costs of publication of this article were defrayed in part by the payment of page charges.
This article must therefore be hereby marked advertisement in accordance with 18 U.S.C.
Section 1734 solely to indicate this fact.
Requests for reprints: KarlT.Kelsey,DepartmentofGeneticsandComplexDiseases,Harvard
School of Public Health, 665 Huntington Avenue, Boston, MA 02115. Phone: 617-432-3313;
Fax: 617-432-0107; E-mail: Kelsey@hsph.harvard.edu
Copyright D 2006 American Association for Cancer Research.
doi:10.1158/1055-9965.EPI-06-0503
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