Review Article
Volume 3 Issue 4 - October 2017
DOI: 10.19080/RAPSCI.2017.03.555619
Recent Adv Petrochem Sci
Copyright © All rights are reserved by Hassan Al-Haj Ibrahim
Chemical Activation of Syrian Sponge Coke
Hassan Al-Haj Ibrahim*
Al-Baath University, Syria
Submission: September 20, 2017; Published: October 16, 2017
*Corresponding author: Hassan Al-Haj Ibrahim, Al-Baath University, Syria, Email:
Recent Adv Petrochem Sci 3(4): RAPSCI.MS.ID.555619 (2017) 0085
Introduction
Water pollution by aromatic compounds is a serious
problem. Although aromatic compounds are in general non-
polar compounds, their polarity is greater than that of aliphatic
compounds with similar number of carbon atoms and aromatic
compounds are therefore less volatile and easier to dissolve in
water with a very low threshold of detectability by taste or in
water. In fact, few micrograms of aromatic compounds in a liter
of water are suf ficient to make the water undrinkable or less
suitable for drinking [1].
Polycyclic aromatic compounds are poisonous and possibly
carcinogenic pollutants. They are, furthermore, semi volatile
and semi stable and not easily disposed of or decomposed by
living organisms. Their presence in water may also render
ineffective the biological treatment of water. Crude oil often
contains certain amounts of such compounds, particularly
naphthalene and methyl naphthalene, which are released on
incomplete combustion [2] or from coking and other plants.
Analysis of sewage and used water often reveals their presence
and their amounts in water are controlled in international
water specifications [3]. In this study, naphthalene was used as
an example of other polycyclic aromatic compounds because of
its high content in used industrial waters.
Naphthalene (C10H8) is a bicyclic aromatic compound
with an equivalent carbon number of 11.69. It is a white,
volatile, crystalline solid that is easily sublimated at normal
temperatures. It is normally used for cloth protection from bugs
and insects. Its solubility in water is about 30mg per liter, and
water may be considered polluted if its naphthalene content
is greater than 0.1mg/liter [1]. Exposure to naphthalene may
have adverse effects on red blood cells and may cause sickness,
diarrhea, nausea and jaundice. Naphthalene is a carcinogenic
substance according to the International Cancer Research
Agency. Naphthalene powder may also form with air an
explosive mixture.
Current research indicates that adsorption is one of the
most effective methods for treatment of water polluted with
aromatic compounds, which are easily adsorbed. These include
naphthalene, polycyclic aromatics, insecticides, herbicides
and high molecular-weight compounds such as dyes, gasoline
and amines. Most research on the adsorption of polycyclic
compounds has been concerned with adsorption in the gaseous
phase with much less work on adsorption form aqueous
solutions [4,5]. Adsorption from complex multi-component
aqueous solutions is much more complicated than adsorption
from the gaseous phase. This is mainly due to the possible
interactions between the different components and their effect
on the adsorbent’s selectivity in the adsorption of the dissolved
substances in preference to the adsorption of the solvent.
This is especially apparent in dilute solutions with a high
solvent concentration as in the case of solutions of polycyclic
compounds in water.
Carbon adsorption is an effective water treatment method.
It was used from ancient times in water treatment. Arabs in
Abstract
Syrian sponge coke activated by treatment with molten potassium hydroxide is used in the adsorption of naphthalene from water. Some
of the factors that are expected to affect the process of adsorption are also investigated. The results obtained indicate that the adsorption of
naphthalene by activated coke can be represented by the Langmuir and Freundlich equations.
Keywords: Activated carbon; Petroleum coke; Adsorption; Naphthalene
Recent Advances in
Petrochemical Science
ISSN: 2575-8578