Research Article Open Access
Volume 5 • Issue 6 • 1000327
J Environ Anal Toxicol
ISSN: 2161-0525 JEAT, an open access journal
Open Access Review Article
Tantry et al., J Environ Anal Toxicol 2015, 5:6
DOI: 10.4172/2161-0525.1000327
*Corresponding author: Bilal Ahmad Tantry, Department of Microbiology,
College of Medicine, Aljouf University, Saudi Arabia, Tel: 966506281724;
E-mail: batantry@ju.edu.sa
Received August 17, 2015; Accepted October 25, 2015; Published October 28,
2015
Citation: Tantry BA, Shrivastava D, Taher I, Tantry MN (2015) Arsenic Exposure:
Mechanisms of Action and Related Health Effects. J Environ Anal Toxicol 5: 327.
doi:10.4172/2161-0525.1000327
Copyright: © 2015 Tantry BA, et al. This is an open-access article distributed under
the terms of the Creative Commons Attribution License, which permits unrestricted
use, distribution, and reproduction in any medium, provided the original author and
source are credited.
Arsenic Exposure: Mechanisms of Action and Related Health Effects
Bilal Ahmad Tantry
1,2*
, Divya Shrivastava
2
, Ibrahim Taher
1
and Mudasar Nabi Tantry
3
1
Department of Microbiology, College of Medicine, Aljouf University, Saudi Arabia
2
School of Life Sciences, Jaipur National University, Jaipur, India
3
Department of Clinical Biochemistry, Kashmir University, India
Keywords: Arsenic health efects; Arsenic; Cancer; Arsenic
metabolism; Chronic arsenic exposure; Drinking water
Introduction
For many centuries, Arsenic (As) has almost exclusively been
connected with deliberate poisoning, but in the contemporary world,
it has largely contributed to escalating environmental pollution. Te
widespread anthropogenic use of pesticides containing arsenic can
adversely afect human health. In addition, the activities that involves
mining and burning of coal, thereby releasing it in the air has received
pivotal attention [1]. Arsenic difers in its form when food and
drinking water are concerned. In food, arsenic is found in both organic
and inorganic form, depending on the kind of food, whereas, arsenic
is present in inorganic form (either as As
III
or As
V
) in drinking water
[2]. Groundwater usually contains arsenic as detected in 70 countries
worldwide that has afected 140 million people. Most of the afected
people live in Asia (such as Bangladesh, India) who have been afected
with concentration levels higher than the WHO drinking water arsenic
value of 10 μg/L as well as the national regulatory standards (e.g., 50
μg/L in India and Bangladesh) [3,4].
Arsenic contamination prevalent in groundwater ofen stems
from geological sources and its consumption can cause chronic health
disorders in numerous afected regions across the globe [5]. In Asia,
arsenic found in groundwater is considered as the largest environmental
health disaster that aims to threaten at least 100 million people in the
Bengal Basin of Bangladesh and West Bengal. Arsenic exposure and
consumption has been afecting India with cancer disease and other As-
related ailments [6]. Arsenic is the 52nd out of 92 elements that is heavily
found in earth’s crust and has a concentration of 1.8 parts per million.
Tis poisonous element occurs naturally in numerous minerals such as
arsenopyrite, tennantite (copper arsenic sulfde) and realgar (arsenic
sulfde). In soils, mostly the inorganic forms of arsenic are found such
as As
III
(arsenite) and AsV (arsenate) [7,8]. Monomethylarsonic acid
(MMAA), Methylated species, trimethylarsine oxide (TMAO) and
dimethylarsinic acid (DMAA) are vastly present in biomass, but soils
also incorporate them [1]. In addition, As
V
and As
III
can be evaporated
at regular temperature for transforming into arsine, MMAA changing
to tomonomethylarsine [9], TMAO transforming to trimethylarsine
(TMA) and DMAA taking shape of dimethylarsine (DMA) [10].
Diferent soil parameters are likely to afect the toxicity and
bioavailability of arsenic prevalent in soil. Soil parameters such as
redox potential, pH, soil and site hydrology can highly infuence the
toxicity of arsenic. In addition, microbial and plant components can
afect the arsenic absorption. Te above-mentioned parameters can
afect the behavior of soil colloids and absorption capacity, thereby
changing the bioavailability and solubility of arsenic [11-13]. In
natural ecosystem settings, the chemical processes can play a pivotal
role in controlling the arsenic exposure and mobility. However, there
are increased chances that microbial metal reduction can also play
an essential role in mobilizing toxic metals that can have disastrous
efects on living beings’ health. Microbial reduction of As
V
and more
poisonous and mobile As
III
species can take place through respiration
processes [14,15].
Numerous bacteria contain the As
V
-reductase gene that is involved
in As
V
reduction [16], only few microorganisms which have the
capability to respire As
V
have been secluded [17]. Te AsV-respiring
bacteria are likely to use various electron donors such as hydrogen
and acetate; and can be of diferent types ranging from mesophiles to
extremophiles [17]. Trough laboratory studies, it has been determined
that microbial phenomena that plays an essential role in reducing and
mobilizing As
V
are more rapid as compared to inorganic chemical
changes [18]. Laboratory researches revealed that these microorganisms
can signifcantly contribute in As cycling in the earth crust [14,18,19].
Arsenic Mechanism of Action and Related Health Efects
Arsenic metabolism
Arsenic can enter human body by drinking impure water and
can act as deterrent to secure health. Hence, arsenic is vulnerable to
human health and can cause cancer also. Tis issue is becoming a
Abstract
Arsenic represents a natural drinking water contaminant that can deteriorate health due to its extreme toxic nature.
Infant mortality, neuropathies, liver disease, cancer, eye diseases, cardiovascular disease and different skin alterations
can stem from chronic arsenic exposure. The predominant species of arsenic comprise of arsenite and arsenate.
Arsenite is more toxic in nature as compared to arsenate. Arsenic pollution is mainly caused by natural process such
as weathering of rocks and minerals followed by leaching and industrial activities that lead to contamination of soil
and groundwater. The WHO guideline permits the maximum limit of arsenic as 10 μg/L in drinking water. This review
provides a comprehensive overview on arsenic mode of action, its sources and health related effects. The effect of
toxicity, biomarkers of arsenic toxicity and the mechanism of arsenic dangers on humans are also discussed.
Journal of
Environmental & Analytical Toxicology
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ISSN: 2161-0525