2538 Microsc. Microanal. 27 (Suppl 1), 2021
doi:10.1017/S143192762100903X © Microscopy Society of America 2021
Investigating Space Weathering Effects on Carbonaceous Asteroids Using High-flux
and Low-flux Ion Irradiation of the Murchison Meteorite
Dara Laczniak
1
, Michelle Thompson
2
, Roy Christoffersen
3
, Catherine Dukes
4
, Simon Clemett
3
, Richard
Morris
5
and Lindsay Keller
5
1
Purdue University - Department of Earth, Atmospheric, and Planetary Sciences, Lafayette, Indiana,
United States,
2
Purdue University - Department of Earth, Atmospheric, and Planetary Sciences, United
States,
3
Jacobs JETS, NASA Johnson Space Center, United States,
4
University of Virginia,
Charlottesville, Virginia, United States,
5
NASA Johnson Space Center, United States
Introduction: Airless planetary bodies are continuously altered by space weathering processes such as
solar wind irradiation and micrometeoroid bombardment. These processes change the microstructural,
chemical, and optical properties of planetary regoliths and, in turn, complicate interpretations of surface
composition from remote sensing data. Previous space weathering investigations have focused primarily
on lunar and ordinary chondrite materials, the latter of which have been linked to S-type asteroids [1].
However, relatively little is known about space weathering of primitive carbonaceous chondrites, which
contain a combination of hydrous silicate and organic phases and are hypothesized to be fragments of C-
complex asteroids [2]. To address this knowledge gap and maximize the science return of missions
targeting C-complex asteroids (e.g., NASA OSIRIS-REx targeting Bennu and JAXA Hayabusa2 targeting
Ryugu) [3-4], we examine the spectral, microstructural, and chemical effects of simulated solar wind
weathering on a carbonaceous asteroid analog material. Here, we present the results from coordinated
analyses of Murchison (CM2) meteorite slabs irradiated with 1 keV/amu H
+
and He
+
ions.
Methods: Dry-cut Murchison slabs were exposed to 1 keV H
+
and 4 keV He
+
irradiation under ultra-high
vacuum (10
-8
Pa). For the first set of experiments, we used a high ion flux of ~1.0x10
13
ions/cm
2
/s. H
+
-
irradiation reached a total fluence of 8.1x10
17
H
+
/cm
2
(~700 yrs exposure at Bennu) while He
+
-irradiation
reached a total fluence of 1.1x10
18
He
+
/cm
2
(~23,000 yrs at Bennu). For the second set, we used lower
ion fluxes—6.6x10
11
H
+
/cm
2
/s and 3.6x10
11
He
+
/cm
2
/s—to more closely simulate the ion flux of actual
solar wind (10
8
ions/cm
2
/s). H
+
-irradiation reached a total fluence of 4.0x10
16
H
+
/cm
2
(~20 yrs at Bennu)
while He
+
-irradiation reached a total fluence of 2.1x10
16
He
+
/cm
2
(~400 yrs at Bennu). To characterize
the unirradiated, H
+
-irradiated, and He
+
-irradiated surfaces, we perform five coordinated analytical
techniques. Changes in surface chemistry are observed with in situ X-ray photoelectron spectroscopy
(XPS) using a PHI Versaprobe III Scanning XPS. Changes in spectral slope, surface albedo, and
absorption band strengths are evaluated using visible to near-infrared spectra (VNIR; 0.35 – 2.50 μm)
acquired with a fiber-optic ASD FieldSpec 3 Spectrometer. Modifications to organic chemistry are
investigated using microprobe two-step laser-desorption mass spectrometry (μL
2
MS). For transmission
electron microscopy (TEM), we prepare four electron transparent cross sections consisting of matrix
material, Mg-rich olivine, Fe-rich olivine, and pyroxene, respectively, from each H
+
- and He
+
-irradiated
region using a Quanta 3D DualBeam field emission focused ion beam scanning electron microscope.
Lastly, we use a JEOL 2500SE 200 kV field-emission scanning transmission electron microscope
equipped with a 60 mm
2
ultra-thin window silicon drift energy dispersive X-ray (EDX) detector to
examine the microstructure and composition of ion-affected rims in each FIB-section.
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