Effect of Silica Morphology on the Structure of Hard- Templated, Non-Precious Metal Catalysts for Oxygen Reduction Jacob Anibal 1 , Henry G. Romero 2 , Nathaniel D. Leonard 1 , Cenk Gumeci 1 , Barr Halevi 2 , Scott Calabrese Barton 1* 1 Department of Chemical Engineering and Materials Science, Michigan State University, East Lansing, MI 48824(USA) 2 Pajarito Powder, Albuquerque, NM 87102 (USA) Abstract With extensive development over the past ten years, non-precious metal (NPM) catalysts have become promising alternatives to platinum catalysts in fuel cell cathodes, but have been challenged by severe transport limitations. Hard template synthesis, also called the sacrificial support method, promises to improve transport properties introducing a sacrificial template to form mesopores. To further understand hard template transport properties, the relationship between template morphology, resulting catalyst pore structure, and overall fuel cell performance was investigated. Porous carbon materials and catalysts were synthesized using four different silica templates. Nitrogen physisorption and scanning electron microscopy were used to characterize pore diameter and morphology. The catalysts displayed pores approximately half the diameter of the template particles, and a geometric model is proposed to describe pore collapse. Catalyst electrochemical performance was characterized in membrane electrode assemblies using * Corresponding Author. E-mail: scb@msu.edu (Scott Calabrese Barton), tel: +1-517-355-0222 © 2016. This manuscript version is made available under the Elsevier user license http://www.elsevier.com/open-access/userlicense/1.0/