© 2014 Lammini, A., A. Dehbi, H. Omari and A. Abdallaoui. This open access article is distributed under a Creative
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American Journal of Geosciences
Original Research Paper
Study of Heavy Metals in the Surface Sediments of the Main
Wadis in the Region of Meknes-Morocco
Lammini, A., A. Dehbi, H. Omari and A. Abdallaoui
Department of Chemistry, Analytical Chemistry and Environment Team, Faculty of Sciences,
Moulay Ismail University, PO Box 11201, Zitoune, Meknes, Morocco
Article history
Received: 12-12-2015
Revised: 01-08-2015
Accepted: 02-02-215
Corresponding Author:
Abdallaoui, A.
Department of Chemistry,
Analytical Chemistry and
Environment Team, Faculty of
Sciences, Moulay Ismail
University, PO Box 11201,
Zitoune, Meknes, Morocco
Email: a.abdallaoui@gmail.com
Abstract: Because of their growing demographic and industrial expansion,
the urban areas of the city of Meknes are likely to disturb the ecological
balance of watercourse. In the present work, we had evaluate the degree of
sediment’s contamination by heavy metals (Al, Cd, Cu, Fe, Mn, Pb and Zn)
in the main wadis of the Meknes region (Boufekrane, Wislane and Toulal)
which are tributaries of the oued R’doom. These heavy metals were assayed
by ICP, after the sediment mineralization by aqua regia. Reference
concentrations were determined by the method of coring. In parallel to this
and for the characterization of the studied sediments, we also determined
the physico-chemical parameters: Carbonates, organic matter, pH and
granulometry. The analysis of the whole data collected by a multivariate
statistical method (factorial correspondence analysis) allowed us to
distinguish five groups of heavy metals.
Keywords: AFC, Watercourse, Heavy Metals, Pollution, Sediment
Introduction
The aquatic environment pollution has become one
of the most serious nuisances, notably, that affects
urban and industrial areas. The anthropic activities
remain the main cause of the degradation of the
quality of water in the surface: Wastewater
discharges, agricultural activities notably the
excessive use of fertilizers and pesticides.
However, the degree of pollution of the aquatic
environment by heavy metals cannot always be
evaluated only on the basis of their concentration in
water. Indeed, on the one hand, the concentrations of
heavy metals in the water are close to the detection
levels limits where the uncertainty range is large
enough. On the other hand, the heavy metals are
subtracted from water by multiple processes and the
concentrations consequently do not reflect the real
significance of pollution owed to human activities,
which accelerates the process of degradation of the
quality of the wadis (Saadallah, 1991).
The analysis of metals in sediments appears to be a
lane that allows circumventing these difficulties.
Elsewhere, the process of exchange of heavy
metals at the water-sediment interface in particular, in
relationship with adsorption and desorption equilibria,
depend of the physicochemical parameters such as
organic matter, carbonates, pH and the granulometry.
For example an increase in pH
promotes the adsorption of selected heavy metals on
the reducible fraction of sediments (iron and
manganese oxides), (Vanthuyne et al., 2003; Basta and
Tabatabal, 1992a; 1992b; Kribi, 2005; Zhu and Alva,
1993; Tessier et al., 1990).
We therefore judged it important to determine the
physicochemical parameters and evaluate metal
concentrations of seven heavy metals; aluminum,
cadmium, copper, iron, manganese, lead and zinc; of
sediment deposited in the level of three main wadis of
the Meknes region: Wislane, Boufekrane and Toulal.
Materials and Methods
Study Sites
The sites of our work are the Wadis of Wislane,
Boufekrane and Toulal, which play an important socio-
economic role for the Region of Meknes; one of the most
agricultural regions in Morocco.
Boufekrane Wadi is a permanent watercourse of
the Sais plain. It flows through the lake basin of
Meknes plateau, whose substratum consists of sandy
limestone of Pliocène and its coverage (agricultural
land) of Tertiary and Quaternary Age. It rises to the
west of El Hajeb, in the Middle-Atas, 750 m above
sea level (Saadallah, 1991). It holds the name of Aïn
Maarouf near the source, then that of Boufekrane 10
km from it, until after its confluence in the first place