Volume 6 • Issue 5 • 1000446
J Food Process Technol
ISSN: 2157-7110 JFPT, an open access journal
Open Access Research Article
Ogutu et al., J Food Process Technol 2015, 6:5
DOI: 10.4172/2157-7110.1000446
*Corresonding author: Fredrick Onyango Ogutu, Laboratory of Food Chemistry
and Nutritional Sciences, Institute of Agro-product products Processing Science
and Technology of the Chinese Academy of Agricultural Sciences, Beijing, China,
Tel: +86 13021072954; E-mail: fogutu0@gmail.com
Received March 16, 2015; Accepted April 08, 2015; Published April 15, 2015
Citation: Ogutu FO, Mu T, Elahi R, Zhang M, Sun H (2015) Ultrasonic Modifcation
of Selected Polysaccharides-Review. J Food Process Technol 6: 446.
doi:10.4172/2157-7110.1000446
Copyright: © 2015 Ogutu FO, et al. This is an open-access article distributed under
the terms of the Creative Commons Attribution License, which permits unrestricted
use, distribution, and reproduction in any medium, provided the original author and
source are credited.
Abstract
This review is a survey on ultrasonic application in selected carbohydrate polymers based upon available research reports.
It covers a brief discussion on the fundamentals of ultrasound technology, before delving on the effects of ultrasound on specifc
polymers; pectin, chitin, starch, carrageenan and guar gum, their modifcation products and possible applications in food,
pharmaceutical, biomedical and packaging sectors. Sonication generally leads to depolymerization and side chain break within
molecules resulting into oligosugars. Oligosugars are widely used as prebiotics and specifc delivery systems; moreover, nano
sized products of sonication can be applied in diverse felds. Presently, ultrasonic is fnding application in wider sectors therefore
better understanding of the complex physico-chemical changes and mechanism of the action of high-intensity ultrasound and its
effect on techno-functional properties of compounds would immensely fortify the application of ultrasonic technology.
Ultrasonic Modification of Selected Polysaccharides-Review
Fredrick Onyango Ogutu
1,2*
, Tai-Hua Mu
1
, Rizwan Elahi
1
, Miao Zhang
1
and Hong-Nan Sun
1
1
Laboratory of Food Chemistry and Nutritional Sciences, Institute of Agro-product products Processing Science and Technology of the Chinese Academy of Agricultural
Sciences, Beijing, China
2
Food Technology Division, Kenya Industrial Research and Development Institute (KIRDI), Nairobi-Kenya
Keywords: Sonication; Oligosaccharides; Cavitation; Depolymerization;
Modifcation; Functional
Introduction
Carbohydrate polymers are the most abundant organic
resources in nature with cellulose, chitin and starch being the most
abundant, they consist of polymeric structures, formed by repeating
units of monosaccharide joined together by 0- glycosidic bonds
[1]. Carbohydrate polymers are quite diverse based upon their
monosaccharide composition, bond linkage type, branching, degrees of
polymerization and cone shape [2]. Te polymers are widely applied in
food, cosmetic, pharmaceutical and others sectors [3-6].
Te carbohydrate colloids are mainly applied in food as stabilizers,
emulsifers, thickening and texture improving agents [7,8]. Te colloids
application as food ingredient is based upon their physic-chemical
characteristics, which ofen limit their application. To diversify the
application of the colloids in food and functional food, modifcation
is ofen required to achieve desired quality [9,10]. For instance, colloid
size reduction has been shown to enhance stability in food a system that
requires stabilization [11,12].
Food ingredients and functional food sector has been growing
from the macro scale molecules to micro and currently nano scale [13-
16]. While micro and nano-sized food particles are believed to have
better absorption, stabilization ability and solubility etc. For instance
starch nano crystals use as a reinforcing phase in a polymeric matrix
and as a barrier material in packaging materials nano-emulsion was
also shown to be efective carrier for hydrophobic bioactive molecules
since novel ingredients can be added with negligible impact to solution
clarity. For a long time enzymatic and chemical methods have been the
preferred choice for molecular size reduction in colloids. However, due
to the hazardous nature of chemicals and delicate control in enzymatic
reactions the use of physical methods has been gaining ground [17-
19]. Ultrasonic method is emerging as an easily adaptable, easy to
use and efective method of polymer modifcation as demonstrated
by the numerous research reports [20-23]. Te current review looked
at research papers on sonication of pectin, carrageenan, chitosan,
guar gum and starch. Te aim was to give insight into sonolysis by
extracting the documented pieces of evidence, with a view of aiding
better understanding the underlying process, products and possible
applications.
Ultrasonic is defned as the science and technology of applying
sound waves with frequencies above human hearing ability, essentially
above 20 kHz [24]. Ultrasound can be classifed into two main classes
based upon frequency range i.e. power ultrasound and diagnostic
ultrasound [25]. Power ultrasound is in the average range of 18-100 kHz
and intensity >1 w/m
2
which can be applied in processing and chemical
transformation, while diagnostic ultrasound with frequency above 500
MHz. Power ultrasound may also be referred to as Sonochemistry,
which is the Ultrasound application in materials, chemical reaction and
processes, excluding medical applications [26]. Another classifcation
scheme categorizes ultrasound into three main classes based upon
their frequency and power range as follows; low frequency high power
ultrasound 20-10 kHz, medium frequency medium power ultrasound
100kHz-1MHz and the high frequency low power ultrasound >1 MHz.
Ultrasound with high impact applied in the food industry is in the
range of low and high frequency. However, this defnition is steadily
changing with increasing and expanding applications of ultrasound in
areas like cleaning, measuring quality and fow rate of foods [27,28].
Tis paper reviews the available literature on the application of power
ultrasound to selected carbohydrates polymer and its sonochemical
impact.
General Applications of Ultrasonic in Foods
Ultrasound is a form of energy carried by sound and can be
transformed into other forms energy which is the basis of its applications
[29,30]. Power ultrasound is capable of causing physical and chemical
transformations through acoustic cavitation [31]. Ultrasonic treatment
requires fuid for cavitation to be generated; moreover, some conditions
must be met, for instance the frequency must be between 20 to 100 kHz.
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ISSN: 2157-7110