Vol 2 No 2 (2020) e-ISSN: 2682-8383
Journal of Engineering Technology and Applied Physics (2020) 2, 2, 6: 36-41
https://doi.org/10.33093/jetap
© The Authors. This article is licensed under Creative Common License.
Published by MMU PRESS. URL: https://journals.mmupress.com/index.php/jetap/index
Investigation of MEH-PPV OLED Assisted by An
IoT Environment Monitoring System
Ibrahim Attia, Guang Liang Ong, Teng Sian Ong, Chen Hon Nee and Seong Shan Yap
*
Faculty of Engineering, Multimedia University, Jalan Multimedia, 63100 Cyberjaya, Selangor, Malaysia.
*seongshan@gmail.com
https://doi.org/10.33093/jetap.2020.2.2.6
Abstract - Single layer organic light emitting diode
(OLED) devices based on poly{[2-methoxy-5-(-
2ethylhexyloxy)-1,4-phenylene]vinylene} (MEH-PPV)
are fabricated and studied in this work. There are several
factors that affect the performance of the fabricated
OLED samples. Some of these factors are related to the
fabrication parameters chosen for the OLED fabrication
process. The effect of concentration and annealing
temperature are investigated. Other environmental
factors such as humidity or temperature affect the
performance of fabricated OLED samples under long
term exposure. An internet of things environment
monitoring system (IoT-EMS) is developed to monitor
and study the effect of these factors on the performance
of the OLED samples. Exposure to humidity is found to
severely degrade the samples. In summary, the optimum
concentration for MEH-PPV is concluded to be 4 mg/ml,
and the best annealing temperature is 90C in this study.
It is also deduced that humidity of 72-75 % caused
degradation of the samples in less than 20 hours.
Keywords— Organic light emitting diodes (OLED),
Electroluminescence (EL), Indium Tin Oxide (ITO), IoT
environment monitoring system (IoT-EMS), degradation,
poly(2-Methoxy-5-(20-Ethyl-Hexoxy)-P-
PhenyleneVinylene) (MEH-PPV).
I. INTRODUCTION
Electroluminescence phenomenon was discovered
in 1907. The discovery changed the history of display
and opened up endless possibilities for newer display
technologies. OLED was discovered later, and showed
that it possesses attractive manufacturing advantages
such as having a lower cost and higher flexibility as
compared to inorganic devices [1].
Electroluminescence behavior from a polymer was first
reported in 1990 [2] and since then it was discovered in
a wide range of polymers [3]. One of the polymers that
allowed low voltage operation is PPV based polymers
such as MEH-PPV [4,5].
The efficiency of the fabricated OLED sample can
be optimized by controlling the parameters in the
fabrication processes of said sample. In the fabrication
process, increasing the concentration of the emissive
layer will increase the thickness of the sample.
Changing the annealing temperature will also cause
changes to the OLED’s efficiency. The annealing
temperatures chosen are usually higher than the glass
transition temperature (Tg) of MEH-PPV which is
around 65°C [6] because the electrical characteristics
of the sample depends on the polymer chains. When
heated above Tg, the polymer chains could move freely
and hence enhance the packing of the polymer film.
That will improve the electrical efficiency of the
polymer. As the annealing temperature increases, the
hole injection efficiency also increases, hence,
increasing the electrical efficiency (characteristics) of
the OLED sample [7,8].
There are external factors that affect the OLED’s
efficiency negatively [9]. These external factors cause
the OLED sample to degrade and lose its efficiency
rapidly until the sample fails. There are two types of
degradation, recoverable and unrecoverable [10].
Recoverable degradation occurs a few minutes after a
bias have been applied to the sample; however, a
change in the physical appearance of the sample will be
noticed. Example of recoverable degradation is ionic
impurities. The ionic impurities cause the formation of
internal electric field, which is opposite to the external
applied electric field. After the first forward bias, the
internal electric field is formed and it reduces the
current density in the sample. However, if a reverse
bias is applied to the sample for 10 s, the internal
electrical field can be removed and the current density
of the sample will be improved [10]. Compare to
Journal of Engineering Technology
and Applied Physics